Nitroso compounds have emerged as highly valuable reaction partners or reagents in
organic synthesis due to their rich reactivity. The versatile profile of these compounds allows …

The fluctuating reproducibility of scientific reports presents a well-recognised issue,
frequently stemming from insufficient standardisation, transparency and a lack of information …

Palladium catalyzed tandem reaction represents a one-pot synthetic approach to efficiently
synthesize complex functionalized molecules while reducing synthetic steps, aligning with …

Aziridines are important targets for synthetic chemistry, and many methods involving the
aziridination of alkenes by olefins with nitrenes have been reported. In general, however …

Photolysis of a platinum (II) azide complex in the presence of styrenes enables C═ C
double bond cleavage upon dissociative olefin imination to aldimido (PtII–N═ CHPh) and …

Hypervalent iodine reagents are versatile and readily accessible reagents that have been
extensively applied in contemporary synthesis in modern organic chemistry. Among them …

In this work, the annulation of acyl nitrene with alkynes is reported under photoredox/iron
dual-catalysis for the synthesis of a series of isoquninalin-2-ones. The reaction is featured …

We report on a photochemical reaction of silyl enol ethers with iminoiodinanes. This aza
Rubottom reaction provides a direct access towards α-amino carbonyl compounds under …

Conspectus The potent reactivity of carbenes and nitrenes has been traditionally harnessed
by the employment of a transition-metal catalyst in which the reactivity of the metal …

The radical cascade cyclization of vinyl-tethered alkenes has become a promising tool for
rapidly assembling nonbenzene-fused cyclic skeletons via the cracking of alkenyl C–H …