Optically-pure triptycene-based metallomacrocycles and homochiral self-sorting assisted by ladder formation
Optically-pure triptycene-based metallomacrocycles are, for the first time, synthesized by the
coordination-driven self-assembly of enantiopure triptycene-derived ladder-type bis (benzo …
coordination-driven self-assembly of enantiopure triptycene-derived ladder-type bis (benzo …
Coordination-driven self-assembly of ionic irregular hexagonal metallamacrocycles via an organometallic clip and their cytotoxicity potency
Two new irregular hexagons (6 and 7) were synthesized from a pyrazine motif containing an
organometallic acceptor clip [bearing platinum (II) centers] and different neutral donor …
organometallic acceptor clip [bearing platinum (II) centers] and different neutral donor …
Pyrazine based Pt (II) bis‐alkynyl organometallic complexes: Synthesis, characterization, and cytotoxic effect on A549 human lung carcinoma cells
A facile and efficient synthesis of a series of five new pyrazine‐based organometallic
complexes is being reported. The complexes (2–6) have been fully characterized. Molecules …
complexes is being reported. The complexes (2–6) have been fully characterized. Molecules …
An unusual reaction in nitromethane solution: use of the Cp* Rh moiety to form Prussian blue analogues
H Ma, L Liu, Y Liao, H Shi, P Sun, W Yu - Inorganic Chemistry Frontiers, 2024 - pubs.rsc.org
The direct decomposition of nitromethane into nitrile compounds is a significant challenge
due to the occurrence of severe side-reactions. In this study, we present a novel and gentle …
due to the occurrence of severe side-reactions. In this study, we present a novel and gentle …
Self‐assembled neutral and ionic [2+ 2] metallomacrocycles using a new flexible ditopic Pt (II)‐based organometallic tecton bearing a pyrimidine motif: Facile …
A new di‐platinum (II) organometallic compound (3) has been synthesized from a readily
available pyrimidine derivative in two steps. 3 is a conformationally flexible molecule due to …
available pyrimidine derivative in two steps. 3 is a conformationally flexible molecule due to …
Pyrazine motif containing hexagonal macrocycles: synthesis, characterization, and host–guest chemistry with nitro aromatics
The synthesis and characterization of cationic two-dimensional metallamacrocycles having
a hexagonal shape and cavity are described. Both macrocycles utilize a pyrazine motif …
a hexagonal shape and cavity are described. Both macrocycles utilize a pyrazine motif …
Design of a flexible organometallic tecton: host–guest chemistry with picric acid and self-assembly of platinum macrocycles
The synthesis and characterization of a new pyrazine-based “flexible” and ditopic platinum
(II) organometallic molecule (3) is being reported. Flexibility in this molecule is due to the …
(II) organometallic molecule (3) is being reported. Flexibility in this molecule is due to the …
Pyrazine-based donor tectons: synthesis, self-assembly and characterization
Two new supramolecular building blocks derived from pyrazine are introduced. These
molecules, having pendant pyridine units covalently linked to central pyrazine ring, are …
molecules, having pendant pyridine units covalently linked to central pyrazine ring, are …
Self‐Assembly of [2+ 2] Platina Macrocycles Using a Flexible Organometallic Clip
Synthesis of a new pyrazine‐based “flexible” and ditopic platinum (II) organometallic clip (3)
is being reported. Flexibility is incorporated by ether functional groups that bridge the rigid …
is being reported. Flexibility is incorporated by ether functional groups that bridge the rigid …
Design and synthesis of triptycene based fluorescent polymer with pendent triazole: Effect of functionality on host–guest interaction
Fluorescent materials have emerged as one of the promising candidates for chemical
sensing due to their high sensitivity towards analytes that are relatively electron deficient …
sensing due to their high sensitivity towards analytes that are relatively electron deficient …