Metal-free methods for the generation of benzimidazoles and 2-aminobenzimidazoles

PJ Wanjari, N Saha, G Dubey, PV Bharatam - Tetrahedron, 2023 - Elsevier
Benzimidazoles, the important scaffold of various biologically important molecules, can be
synthesized using metal catalyzed and metal-free methodologies. Recently, metal-free …

Sustainable approaches towards the synthesis of functionalized imidazo [1, 2-a] pyridines: Recent advancements

FA Sofi, K Gogde, D Mukherjee, MH Masoodi - Journal of Molecular …, 2024 - Elsevier
Imidazopyridines are key N-fused heterocycles that have been extensively functionalized by
various synthetic approaches. In the present review, we summarise the recent approaches …

Magnetite dopamine‐decorated copper (Fe3O4@PDA/CuCl2): A robust and reusable catalyst for promoting green synthesis of benzimidazoles and benzothiazoles

M Badbedast, D Khalili, A Abdolmaleki… - Applied …, 2023 - Wiley Online Library
A one‐pot and efficient catalytic protocol has been developed to synthesize
pharmaceutically critical 2‐substituted benzimidazoles and benzothiazoles using magnetite …

Efficient Synthesis of Benzimidazole and Quinoline Derivatives Catalyzed by Functionalized Amidato Ruthenium Complexes in Water via Acceptorless …

X Liu, WZ Dong, Y Liu, WY Shao, Y Li, X Yu… - …, 2023 - Wiley Online Library
Transition‐metal‐catalyzed acceptorless dehydrogenative coupling (ADC) has emerged as
a sustainable synthetic strategy for the construction of N‐heteroaromatics. Herein, a series of …

[HTML][HTML] Sustainable and selective synthesis of benzimidazole scaffolds using deep eutectic solvents

M Shaibuna, K Hiba, AM Shebitha, MJK Kuniyil… - Current Research in …, 2022 - Elsevier
In the present article, the catalytic activity of Zr based DESs (DES 1-DES 3) and Ce based
DESs (DES 4-DES 7) was compared for the synthesis of benzimidazole derivatives. Among …

Ionic‐liquid‐catalyzed synthesis of imines, benzimidazoles, benzothiazoles, quinoxalines and quinolines through C− N, C− S, and C− C bond formation

G Badhani, A Joshi, S Adimurthy - European Journal of Organic …, 2021 - Wiley Online Library
We report the tetramethyl ammonium hydroxide catalyzed oxidative coupling of amines and
alcohols for the synthesis of imines under metal‐free conditions by utilizing oxygen from air …

Visible‐Light‐Driven One‐Pot Synthesis of Benzimidazoles, Benzothiazoles, and Quinazolinones Catalyzed by Scalable and Reusable Ba‐Doped CoMoO4 …

R Abinaya, S Elavarasan, B Binish… - European Journal of …, 2023 - Wiley Online Library
Herein we report a simple and efficient oxidative coupling of various aryl methyl amines with
diverse coupling partners, such as o‐phenylenediamine (benzene‐1, 2‐diamine), 2 …

Tripodal Triazine and 1, 8‐Naphthalimide‐based Small Molecules as Efficient Photocatalysts for Visible‐light Oxidative Condensation

NP Tripathi, S Jain, RK Singh… - Chemistry–A European …, 2024 - Wiley Online Library
Tripodal donor‐acceptor (D‐A) small molecules Tr‐Np3 and Tr‐T‐Np3 consisting of
triphenyl triazine and 1, 8‐naphthalimide, without and with a thiophene spacer have been …

Copper (I) Catalysed Tandem C− C and C− N Bond Cleavage of N‐Fused Imidazoles towards the Synthesis of N‐pyridinylamides

F Ahmad Sofi, MH Masoodi, M Ovais Dar… - …, 2023 - Wiley Online Library
Copper (I) catalysed oxidative conversion of imidazopyridines into N‐pyridinylamides has
been achieved via tandem C− C and C− N bond cleavages under oxidative reaction …

Sodium Copper Chlorophyllin: A Sustainable Bioinspired Catalyst for the Aerobic Oxidative Synthesis of Nitrogen Heterocycles and the Oxidative Cyanation of Tertiary …

SA Pawar, S Gije, C Kalantre, VH Dalvi… - …, 2024 - Wiley Online Library
A remarkably simple and straightforward protocol has been reported showcasing sodium
copper chlorophyllin (SCC) as an eco‐friendly, bioinspired catalyst for the aerobic oxidative …