Photochromism of diarylethene molecules and crystals: memories, switches, and actuators

M Irie, T Fukaminato, K Matsuda, S Kobatake - Chemical Reviews, 2014 - ACS Publications
Photochromism is defined as a reversible transformation of a chemical species between two
isomers having different absorption spectra induced in one or both directions by …

Helicenes: synthesis and applications

Y Shen, CF Chen - Chemical reviews, 2012 - ACS Publications
Helicenes are polycyclic aromatic compounds with nonplanar screw-shaped skeletons
formed by ortho-fused benzene or other aromatic rings. 1, 2 The first helicenes 1 and 2 …

One hundred years of helicene chemistry. Part 3: applications and properties of carbohelicenes

M Gingras - Chemical Society Reviews, 2013 - pubs.rsc.org
Carbohelicenes are a class of fascinating chiral helical molecules which have a rich history
in chemistry. Over a period of almost 100 years, chemists have developed many methods to …

Main-group-based electro-and photoactive chiral materials

F Pop, N Zigon, N Avarvari - Chemical reviews, 2019 - ACS Publications
This Review discusses the structure–property relationships in chiral molecules,
macromolecules (polymers), and supramolecules (crystals, liquid crystals, or thin films) …

[HTML][HTML] Helicene-based chiroptical switches

H Isla, J Crassous - Comptes Rendus Chimie, 2016 - Elsevier
Helicenes are molecules with ortho-fused aromatic rings that adopt an inherently chiral
helical shape. This helical topology combined with the extended π-conjugated system …

Near-Infrared, Organic Chiroptic Switch with High Dissymmetry Factors

ST Bao, S Louie, H Jiang, Q Jiang, S Sun… - Journal of the …, 2023 - ACS Publications
Here we unveil a chiral molecular redox switch derived from PDI-based twistacenes─ c
hPDI [2] that has the remarkable attributes of high-intensity and a broadband chiral …

Dimethylcethrene: a chiroptical diradicaloid photoswitch

P Ravat, T Šolomek, D Häussinger… - Journal of the …, 2018 - ACS Publications
We describe the synthesis and properties of 13, 14-dimethylcethrene, a prototype of a chiral
diradicaloid photochemical switch that can be transformed reversibly via conrotatory …

Synthesis for the mesomer and racemate of thiophene-based double helicene under irradiation

X Liu, P Yu, L Xu, J Yang, J Shi, Z Wang… - The Journal of …, 2013 - ACS Publications
In this work, the racemate and mesomer of the thiophene-based naphthalene-cored double
helicenes (1) were obtained efficiently by one-pot photocyclization of 1, 1, 2, 2-tetrakis …

Chiral Helicenoid Diarylethene with Large Change in Specific Optical Rotation by Photochromism1,2

T Okuyama, Y Tani, K Miyake… - The Journal of Organic …, 2007 - ACS Publications
A diarylethene possessing one [4] thiaheterohelicene and one benzothiophene, the latter
with a chiral methoxymethoxyethyl group on its C-3 position, was proved to work as a switch …

Light-mediated chiroptical switching of an achiral foldamer host in presence of a carbohydrate guest

S Pramanik, B Kauffmann, S Hecht… - Chemical …, 2021 - pubs.rsc.org
A photoresponsive diarylethene was incorporated in an achiral helical foldamer container. A
carbohydrate guest was found to induce opposite handedness upon binding to the open …