Tin halide perovskites: from fundamental properties to solar cells

M Pitaro, EK Tekelenburg, S Shao… - Advanced Materials, 2022 - Wiley Online Library
Metal halide perovskites have unique optical and electrical properties, which make them an
excellent class of materials for a broad spectrum of optoelectronic applications. However, it …

Efficient Lone-Pair-Driven Luminescence: Structure–Property Relationships in Emissive 5s2 Metal Halides

KM McCall, V Morad, BM Benin… - ACS materials …, 2020 - ACS Publications
Low-dimensional metal halides have been the focus of intense investigations in recent years
following the success of hybrid lead halide perovskites as optoelectronic materials. In …

Structural analysis of molecular materials using the pair distribution function

MW Terban, SJL Billinge - Chemical Reviews, 2021 - ACS Publications
This is a review of atomic pair distribution function (PDF) analysis as applied to the study of
molecular materials. The PDF method is a powerful approach to study short-and …

All-inorganic cesium lead iodide perovskite solar cells with stabilized efficiency beyond 15%

K Wang, Z Jin, L Liang, H Bian, D Bai, H Wang… - Nature …, 2018 - nature.com
As the black cesium lead iodide (CsPbI3) tends to transit into a yellow δ-phase at ambient, it
is imperative to develop a stabilized black phase for photovoltaic applications. Herein, we …

Anharmonicity and disorder in the black phases of cesium lead iodide used for stable inorganic perovskite solar cells

A Marronnier, G Roma, S Boyer-Richard… - ACS …, 2018 - ACS Publications
Hybrid organic–inorganic perovskites emerged as a new generation of absorber materials
for high-efficiency low-cost solar cells in 2009. Very recently, fully inorganic perovskite …

“Unleaded” perovskites: status quo and future prospects of tin‐based perovskite solar cells

W Ke, CC Stoumpos, MG Kanatzidis - Advanced Materials, 2019 - Wiley Online Library
The tremendous interest focused on organic–inorganic halide perovskites since 2012
derives from their unique optical and electrical properties, which make them excellent …

Understanding Electron–Phonon Interactions in 3D Lead Halide Perovskites from the Stereochemical Expression of 6s2 Lone Pairs

X Huang, X Li, Y Tao, S Guo, J Gu… - Journal of the …, 2022 - ACS Publications
The electron–phonon (e–ph) interaction in lead halide perovskites (LHPs) plays a role in a
variety of physical phenomena. Unveiling how the local lattice distortion responds to charge …

Stereochemical expression of ns2 electron pairs in metal halide perovskites

Y Fu, S Jin, XY Zhu - Nature Reviews Chemistry, 2021 - nature.com
Metal halide perovskites (MHPs) are characterized as strongly anharmonic and dynamic
lattices. While there is a consensus on the solvation-like polarization effect in these …

The significance of polarons and dynamic disorder in halide perovskites

MJ Schilcher, PJ Robinson, DJ Abramovitch… - ACS Energy …, 2021 - ACS Publications
The development of halide perovskite semiconductors led to various technological
breakthroughs in optoelectronics, in particular in the areas of photovoltaics and light-emitting …

Two-dimensional overdamped fluctuations of the soft perovskite lattice in CsPbBr3

T Lanigan-Atkins, X He, MJ Krogstad, DM Pajerowski… - Nature materials, 2021 - nature.com
Lead halide perovskites exhibit structural instabilities and large atomic fluctuations thought
to impact their optical and thermal properties, yet detailed structural and temporal …