Large amplitude oscillatory shear flow: Microstructural assessment of polymeric systems

M Kamkar, R Salehiyan, TB Goudoulas… - Progress in Polymer …, 2022 - Elsevier
Since the first publications of large amplitude oscillatory shear (LAOS) responses of
polymeric materials in the 1960s, different approaches have been developed to express …

Comb and bottlebrush polymers with superior rheological and mechanical properties

M Abbasi, L Faust, M Wilhelm - Advanced Materials, 2019 - Wiley Online Library
Comb and bottlebrush polymers present a wide range of rheological and mechanical
properties that can be controlled through their molecular characteristics, such as the …

Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization

T Pan, S Dutta, Y Kamble, BB Patel… - Chemistry of …, 2022 - ACS Publications
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …

[HTML][HTML] Single polymer dynamics for molecular rheology

CM Schroeder - Journal of Rheology, 2018 - pubs.aip.org
Single polymer dynamics offers a powerful approach to study molecular-level interactions
and dynamic microstructure in materials. Direct visualization of single polymer chains has …

Linear and extensional rheology of model branched polystyrenes: From loosely grafted combs to bottlebrushes

M Abbasi, L Faust, K Riazi, M Wilhelm - Macromolecules, 2017 - ACS Publications
Monodisperse comb polystyrenes (comb-PS) with loosely to densely grafted architectures
up to loosely grafted bottlebrush structures were synthesized via anionic polymerization …

Effect of side chain length in polystyrene POM–POMs on melt rheology and solid mechanical fatigue

MC Röpert, MG Schußmann, MK Esfahani… - …, 2022 - ACS Publications
The POM–POM architecture is the simplest yet defined branched architecture, showing both
strain hardening in elongation and strain softening in shear. The molecular structure …

Structure and properties of reactively extruded opaque post-consumer recycled PET

MV Candal, M Safari, M Fernández, I Otaegi, A Múgica… - Polymers, 2021 - mdpi.com
The recyclability of opaque PET, which contains TiO2 nanoparticles, has not been as well-
studied as that of transparent PET. The objective of this work is to recycle post-consumer …

Start-up shear flow of a well-characterized entangled H-polymer

F Snijkers, H Lee, T Chang, C Das… - European Polymer …, 2024 - Elsevier
We present a systematic investigation of the linear viscoelasticity and nonlinear start-up
shear flow response of a well-characterized H-polystyrene, an archetype branched polymer …

[HTML][HTML] Hyperstretching in elongational flow of densely grafted comb and branch-on-branch model polystyrenes

V Hirschberg, L Faust, M Abbasi, Q Huang… - Journal of …, 2024 - pubs.aip.org
Strain hardening of long-chain branched polymers in elongational flow occurs due to the
stretch of the backbone chain between branch points. With an increasing number of side …

Impact of topological parameters on melt rheological properties and foamability of PS POM-POMs

MC Röpert, V Hirschberg, MG Schußmann… - …, 2023 - ACS Publications
Rheological properties highly impact the foaming behavior of polymers, as a high melt
strength and low shear viscosity support cell expansion by reducing cell coalescence and …