Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Asymmetric allylic alkylation mediated by transition metals provides an efficient strategy to
form quaternary stereogenic centers. While this transformation is dominated by the use of …

The enantioconvergent cross-coupling of racemic alkyl halides represents a powerful tool for
the synthesis of enantioenriched molecules. In this regard, the first-row transition metal …

Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐or
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …

Propargylamines are a versatile class of compounds which find broad application in many
fields of chemistry. This review aims to describe the different strategies developed so far for …

In the past few decades, it has become clear that asymmetric catalysis is one of the most
powerful methods for the construction of carbon–carbon as well as carbon–heteroatom …

Catalytic asymmetric C–C bond formation with alkylcopper intermediates as carbon
nucleophiles is now textbook chemistry. Related chemistry with boron and silicon …

A copper (I)-catalyzed asymmetric alkylation of HPAr1Ar2 with alkyl halides is uncovered,
which provides an array of P-stereogenic phosphines in generally high yield and …

Abstract An asymmetric catalytic decarboxylative [4+ 2] annulation of 4‐ethynyl
dihydrobenzooxazinones and carboxylic acids has been established by cooperative copper …