1. INTRODUCTION A timely subtitle to this Review focused on conversions of isocyanides at
metal centers could have been “a platinum jubilee of the first metal-mediated reaction …

N-Heterocyclic carbenes (NHCs) are cyclic carbenes bearing at least one R-amino
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …

More than a quarter of a century after the first metal template synthesis of a [2] catenane in
Strasbourg, there now exists a plethora of strategies available for the construction of …

Iron is the most abundant transition metal in Earth, s crust; it is relatively inexpensive, not
very toxic, and environmentally benign. 1 Undoubtedly, due to the involvement in a multitude …

N-Heterocyclic carbenes (NHCs) are omnipresent ligands in coordination and
organometallic chemistry, which is reflected by myriads of applications involving NHC …

Complexes bearing protic N-heterocyclic carbenes (protic NHCs, pNHCs), defined as cyclic
carbenes stabilized by two heteroatoms including at least one NH group, have been less …

CN Bond Cleavage and Ring Expansion of N‐Heterocyclic Carbenes using Hydrosilanes ×
Close The Infona portal uses cookies, ie strings of text saved by a browser on the user's …

Mechanistic studies of the hydrogenolysis of aryl ethers by nickel were undertaken with
(diphosphine) aryl methyl ethers. A Ni (0) complex containing Ni–arene interactions …

This tutorial review summarizes all works and highlights recent advances published in the
growing field of group 7 N-heterocyclic carbene (NHC) complexes. It provides a valuable …

The review describes methods for the preparation of complexes bearing protic NHC ligands,
ie NHCs featuring an NH, NH or NH, NR substitution pattern. The protic NHC ligands are …