Comprehensive overview of polyoxometalates for electrocatalytic hydrogen evolution reaction

Z Zeb, Y Huang, L Chen, W Zhou, M Liao… - Coordination Chemistry …, 2023 - Elsevier
Electrocatalytic water splitting via hydrogen evolution reaction (HER) from renewable energy
sources is an attractive alternative to produce hydrogen, but it still encounters the limitations …

Recent advances of mixed-transition-metal-substituted polyoxometalates

Z Wang, X Xin, M Zhang, Z Li, H Lv, GY Yang - Science China Chemistry, 2022 - Springer
Polyoxometalates (POMs) have been emerging as one of the most widely-studied
interdisciplinary research fields of inorganic chemistry due to their structural diversities and …

Developing insoluble polyoxometalate clusters to bridge homogeneous and heterogeneous water oxidation photocatalysis

Q Hu, S Chen, T Wågberg, H Zhou, S Li… - Angewandte Chemie …, 2023 - Wiley Online Library
Cluster catalysts are attractive for their atomically precise structures, defined compositions,
tunable coordination environments, uniform active sites, and their ability to transfer multiple …

Ion Pairing of Cationic and Anionic Ir(III) Photosensitizers for Photocatalytic CO2 Reduction at Lipid–Membrane Surfaces

S Takizawa, T Okuyama, S Yamazaki… - Journal of the …, 2023 - ACS Publications
We synthesized an ion pair comprising cationic and anionic Ir (III) photosensitizers ([Ir1+][Ir2–
]) for photocatalytic CO2 reduction and showed that the cationic component imparts stability …

Unraveling photocatalytic electron transfer mechanism in polyoxometalate-encapsulated metal-organic frameworks for high-efficient CO2 reduction reaction

J Du, YY Ma, WJ Cui, SM Zhang, ZG Han, RH Li… - Applied Catalysis B …, 2022 - Elsevier
Unraveling the fundamental electron transfer mechanism is vital to deeply understand the
heterogeneous photocatalysis process so as to develop new efficient photocatalysts. Herein …

Ultrathin ZnIn2S4 nanosheets-supported metallic Ni3FeN for photocatalytic coupled selective alcohol oxidation and H2 evolution

M Li, W Qi, J Yu, L Shen, X Yang, S Liu… - Chinese Journal of …, 2022 - Elsevier
Photocatalytic anaerobic organic oxidation coupled with H 2 evolution represents an
advanced solar energy utilization strategy for the coproduction of clean fuel and fine …

Coupling Ni-substituted polyoxometalate catalysts with water-soluble CdSe quantum dots for ultraefficient photogeneration of hydrogen under visible light

M Zhang, X Xin, Y Feng, J Zhang, H Lv… - Applied Catalysis B …, 2022 - Elsevier
The development of robust and efficient hydrogen-evolving system remains a substantial but
promising challenge to convert solar energy into clean fuel. Herein, we report the …

A H4SiW12O40-catalyzed three-component tandem reaction for the synthesis of 3, 3-disubstituted isoindolinones

Y Liu, G Zeng, Y Cheng, L Chen, Y Liu, Y Wei… - Chinese Chemical …, 2024 - Elsevier
Abstract AH 4 SiW 12 O 40-catalyzed three-component tandem reaction of 2-acylbenzoic
acids, primary amines and phosphine oxides to form 3, 3-disubstituted isoindolinones was …

Polyoxometalate‐Based Single‐Atom Catalyst with Precise Structure and Extremely Exposed Active Site for Efficient H2 Evolution

ZR Zhang, HY Sui, WX Shi, J Ren, S Yao… - Angewandte Chemie …, 2024 - Wiley Online Library
Single‐atom catalysts with precise structure and extremely high catalytic efficiency remain a
fervent focus in the fields of materials chemistry and catalytic science. Herein, a nickel …

Highly selective hydrogenolysis of lignin β-O-4 models by a coupled polyoxometalate/CdS photocatalytic system

M Zhang, Z Li, Y Feng, X Xin, GY Yang, H Lv - Green Chemistry, 2023 - pubs.rsc.org
Selective hydrogenolysis of abundant C–O bonds of β-O-4 linkages in natural lignin or lignin
models has been considered as a key strategy for the generation of value-added organic …