A facile method for the synthesis of challenging medium-sized cyclic ethers has been
developed via a novel oxidative rearrangement of benzylic tertiary alcohols. The reaction …

A copper-catalyzed anti-Markovnikov hydrosilylation of alkynes with PhSiH3 was reported.
This reaction represents a notable and efficient example on copper-catalyzed …

A porous organic polymer (POL-Xantphos) was synthesized and employed as a
heterogeneous ligand for selective hydrosilylation of alkynes. It exhibits high selectivity and …

A cobalt/POL-PPh3 catalyzed (E)-selective hydrosilylation of alkynes with PhSiH3 has been
developed for the synthesis of (E)-β-vinylsilanes with high regio-and stereoselectivity and …

This chapter presents the hydrosilylation processes and gives a brief account of the main
types of reactions related to hydrosilylation in which the intermediates with a metal‐silicon …

K2PtCl4/Xphos-SO3Na in a mixture of poly (ethylene glycol)(PEG-400) and water is shown
to be a highly regio-and stereoselective catalyst for the hydrosilylation of terminal alkynes …

This chapter summarizes recent advances of group 10 transition metal hydrosilylation
catalysts from 2015 onward. Since the discovery of Speier's catalyst in 1957, homogeneous …

A rapid and stereodefined synthesis of MIDA–boryl vinylsilanes has been achieved through
the hydrosilylation of an alkynylboronic ester. The E products which contain a silyl and boryl …

Our group is primarily interested in the total synthesis of oroidin-based pyrrole-imidazole-
containing marine sponge-derived alkaloids. These pyrrole-imidazole natural products are a …

Catalytic silicon‐carbon or silicon‐heteroatom bond‐forming hydrosilylation has become
increasingly important in synthetic chemistry, catalysis and organosilicon chemistry. Herein …