Covalent organic frameworks (COFs) are a class of organic crystalline porous materials
discovered in the early 21st century that have become an attractive class of emerging …

The exploitation of competent electrocatalysts is a key issue of the broad application of many
promising electrochemical processes, including the hydrogen evolution reaction (HER), the …

Single‐atom alloys hold great promise for electrocatalytic nitrogen reduction reaction (NRR),
while the comprehensive experimental/theoretical investigations of SAAs for the NRR are …

Benefiting from their unique structural merits, three-dimensional (3D) large-pore COF
materials demonstrate high surface areas and interconnected large channels, which makes …

Modulation of the local electronic structure and microenvironment of catalytic metal sites
plays a critical role in electrocatalysis, yet remains a grand challenge. Herein, PdCu …

Vinylene/olefin-linked two-dimensional covalent organic frameworks (v-2D-COFs) have
emerged as advanced semiconducting materials with excellent in-plane conjugation, high …

Rational design of covalent organic frameworks (COFs) to broaden their diversity is highly
desirable but challenging due to the limited, expensive, and complex building blocks …

Precise design and construction of catalysts with satisfied performance for ambient
electrolytic nitrogen reduction reaction (e‐NRR) is extremely challenging. By in situ …

Dithiine linkage formation via a dynamic and self-correcting nucleophilic aromatic
substitution reaction enables the de novo synthesis of a porous thianthrene-based two …

Manipulating the coordination environment of individual active sites in a precise manner
remains an important challenge in electrocatalytic reactions. Herein, inspired by theoretical …