Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Molecular Catalysts for the Reductive Homocoupling of CO2 towards C2+ Compounds

HQ Liang, T Beweries, R Francke… - Angewandte Chemie, 2022 - Wiley Online Library
The conversion of CO2 into multicarbon (C2+) compounds by reductive homocoupling offers
the possibility to transform renewable energy into chemical energy carriers and thereby …

Carbon dioxide reduction with homogenous early transition metal complexes: Opportunities and challenges for developing CO2 catalysis

KA Grice - Coordination Chemistry Reviews, 2017 - Elsevier
The field of carbon dioxide reduction by homogeneous early transition complexes (groups 3–
7) is reviewed. Many reactions with CO 2 have been studied with late transition metal …

Carbon dioxide complexes: Bonding modes and synthetic methods

A Paparo, J Okuda - Coordination Chemistry Reviews, 2017 - Elsevier
A critical survey on the literature on CO 2 metal complexes is provided. A re-evaluation of all
known CO 2 complexes reveals the existence of several bonding modes, which have not …

Recent advances in cooperative activation of CO 2 and N 2 O by bimetallic coordination complexes or binuclear reaction pathways

S Sinhababu, Y Lakliang, NP Mankad - Dalton Transactions, 2022 - pubs.rsc.org
The gaseous small molecules, CO2 and N2O, play important roles in climate change and
ozone layer depletion, and they hold promise as underutilized reagents and chemical …

Solution Synthesis, Structure, and CO2 Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe3)2]3}

DH Woen, GP Chen, JW Ziller, TJ Boyle… - Angewandte Chemie …, 2017 - Wiley Online Library
The first crystallographically characterizable complex of Sc2+,[Sc (NR2) 3]−(R= SiMe3), has
been obtained by LnA3/M reactions (Ln= rare earth metal; A= anionic ligand; M= alkali …

Reductive Cleavage of CO2 by Metal–Ligand-Cooperation Mediated by an Iridium Pincer Complex

M Feller, U Gellrich, A Anaby… - Journal of the …, 2016 - ACS Publications
A unique mode of stoichiometric CO2 activation and reductive splitting based on metal–
ligand-cooperation is described. The novel Ir hydride complexes [(t Bu-PNP*) Ir (H) 2](2)(t Bu …

Aromatic Ester‐Functionalized Ionic Liquid for Highly Efficient CO2 Electrochemical Reduction to Oxalic Acid

Y Yang, H Gao, J Feng, S Zeng, L Liu, L Liu… - …, 2020 - Wiley Online Library
Electrochemical reduction of CO2 into valuable chemicals is a significant route to utilize CO2
resources. Among various electroreduction products, oxalic acid (H2C2O4) is an important …

Revisiting Reduction of CO2 to Oxalate with First-Row Transition Metals: Irreproducibility, Ambiguous Analysis, and Conflicting Reactivity

M Marx, H Frauendorf, A Spannenberg, H Neumann… - JACS Au, 2022 - ACS Publications
Construction of higher C≥ 2 compounds from CO2 constitutes an attractive transformation
inspired by nature's strategy to build carbohydrates. However, controlled C–C bond …