Efficient, selective and sustainable catalysis of carbon dioxide

QW Song, ZH Zhou, LN He - Green Chemistry, 2017 - pubs.rsc.org
Performing CO2 conversion in a cost-effective and environmentally benign manner would
be promising and remains challenging due to its thermodynamic stability and kinetic …

Polymers Based on Cyclic Carbonates as Trait d'Union Between Polymer Chemistry and Sustainable CO2 Utilization

N Yadav, F Seidi, D Crespy, V D'Elia - ChemSusChem, 2019 - Wiley Online Library
Given the large amount of anthropogenic CO2 emissions, it is advantageous to use CO2 as
feedstock for the fabrication of everyday products, such as fuels and materials. An attractive …

Enhancing the Catalytic Performance of Group I, II Metal Halides in the Cycloaddition of CO2 to Epoxides under Atmospheric Conditions by Cooperation with …

W Natongchai, S Posada-Pérez… - The Journal of …, 2022 - ACS Publications
Compared to metal–organic complexes and transition-metal halides, group I metal halides
are attractive catalysts for the crucial cycloaddition reaction of CO2 to epoxides as they are …

En route to CO 2-containing renewable materials: catalytic synthesis of polycarbonates and non-isocyanate polyhydroxyurethanes derived from cyclic carbonates

FD Bobbink, AP van Muyden, PJ Dyson - Chemical Communications, 2019 - pubs.rsc.org
Combining CO2-chemistry with biomass conversion allows renewable polymeric materials
including polycarbonates and polyhydroxyurethanes (PHUs) to be generated. The demand …

Paving way for sustainable earth-abundant metal based catalysts for chemical fixation of CO2 into epoxides for cyclic carbonate formation

D Prasad, KN Patil, NK Chaudhari, H Kim… - Catalysis …, 2022 - Taylor & Francis
The involvement of CO2 as a renewable and abundant feedstock toward a carbon balanced
future has led to production of several value-added products. The primary focus in the …

Salen-type aluminum and zinc complexes as two-faced Janus compounds: contribution to molecular sensing and polymerization catalysis

M Strianese, D Pappalardo, M Mazzeo… - Dalton …, 2020 - pubs.rsc.org
The aim of the present review is to highlight the most recent achievements in different fields
of application of salen-based zinc and aluminum complexes. More specifically this article …

Aluminum porphyrins with quaternary ammonium halides as catalysts for copolymerization of cyclohexene oxide and CO 2: metal–ligand cooperative catalysis

J Deng, M Ratanasak, Y Sako, H Tokuda, C Maeda… - Chemical …, 2020 - pubs.rsc.org
Bifunctional AlIII porphyrins with quaternary ammonium halides, 2-Cl and 2-Br, worked as
excellent catalysts for the copolymerization of cyclohexene oxide (CHO) and CO2 at 120° C …

Vanadium(V) Catalysts with High Activity for the Coupling of Epoxides and CO2: Characterization of a Putative Catalytic Intermediate

C Miceli, J Rintjema, E Martin, EC Escudero-Adan… - ACS …, 2017 - ACS Publications
Vanadium (V) complexes derived from aminotriphenolate ligands are demonstrated to be
highly active catalysts for the coupling of various terminal and internal epoxides with carbon …

Aluminum‐mediated formation of cyclic carbonates: benchmarking catalytic performance metrics

J Rintjema, AW Kleij - ChemSusChem, 2017 - Wiley Online Library
We report a comparative study on the activity of a series of fifteen binary catalysts derived
from various reported aluminum‐based complexes. A benchmarking of their initial rates in …

Synthesis of bio-derived cyclic carbonates from renewable resources

F de la Cruz-Martínez… - ACS Sustainable …, 2019 - ACS Publications
The coupling reaction of carbon dioxide and terminal, internal, and highly substituted
epoxides derived from renewable resources such as furfural, limonene, carvone, carvyl …