Di-iron analogue of [FeFe]-hydrogenase active site as a molecular electro-catalyst for proton reduction

X Zhang, L Liu, W Cao, D Lv - Catalysis Letters, 2020 - Springer
With Me 3 NO being present, the ligand substitution reaction of [(μ-dmedt){Fe (CO) 3} 2] by 4,
4′-bipyridine afforded a new diiron complex (μ-dmedt) Fe 2 (CO) 5 (4, 4′-bipyridine) 1 …

Electrochemical proton reductions catalyzed by the simpler hexacoordinate iron compounds as functional mimics of the active site in [FeFe] hydrogenase

S Gao, QC Liang, Q Duan, DY Jiang, JX Zhao - Electrocatalysis, 2018 - Springer
Ligand-substitution reaction of [(μ-S 2 C 4 N 2 H 2) Fe 2 (CO) 6](1) generated a normal
mono-substituted diiron dithiolate derivative [(μ-S 2 C 4 N 2 H 2) Fe 2 (CO) 5 (PMe 3)](1P) …