Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …

In the pursuit of new pharmaceuticals and agrochemicals, chemists in the life science
industry require access to mild and robust synthetic methodologies to systematically modify …

Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

Alkyl radicals are key intermediates in organic synthesis. Their classic generation from alkyl
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …

The exceptional versatility of sulfones has been extensively exploited in organic synthesis
across several decades. Since the first demonstration in 2005 that sulfones can participate …

Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions
with two different substrates. Similar to conventional electrosynthesis, the primary redox …

Radical–radical coupling, the selective reaction between two different radical species, has
contributed to the methodology for connecting bulky units. Light-driven N-heterocyclic …

An enantioselective protonation strategy has been successfully applied to the synthesis of
chiral α-tertiary azaarenes. With a dual catalytic system involving a chiral phosphoric acid …