Mechanisms of nickel-catalyzed cross-coupling reactions

JB Diccianni, T Diao - Trends in Chemistry, 2019 - cell.com
Advances in nickel-catalyzed cross-coupling reactions have expanded the chemical space
of accessible structures and enabled new synthetic disconnections. The unique properties of …

An evolving view of methane metabolism in the Archaea

PN Evans, JA Boyd, AO Leu, BJ Woodcroft… - Nature Reviews …, 2019 - nature.com
Methane is a key compound in the global carbon cycle that influences both nutrient cycling
and the Earth's climate. A limited number of microorganisms control the flux of biologically …

Ferromagnetic single-atom spin catalyst for boosting water splitting

T Sun, Z Tang, W Zang, Z Li, J Li, Z Li, L Cao… - Nature …, 2023 - nature.com
Heterogeneous single-atom spin catalysts combined with magnetic fields provide a powerful
means for accelerating chemical reactions with enhanced metal utilization and reaction …

Methane formation driven by reactive oxygen species across all living organisms

L Ernst, B Steinfeld, U Barayeu, T Klintzsch, M Kurth… - Nature, 2022 - nature.com
Abstract Methane (CH4), the most abundant hydrocarbon in the atmosphere, originates
largely from biogenic sources linked to an increasing number of organisms occurring in oxic …

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction

HB Yang, SF Hung, S Liu, K Yuan, S Miao, L Zhang… - Nature energy, 2018 - nature.com
Electrochemical reduction of CO2 to chemical fuel offers a promising strategy for managing
the global carbon balance, but presents challenges for chemistry due to the lack of effective …

Electronic Regulation of Nickel Single Atoms by Confined Nickel Nanoparticles for Energy‐Efficient CO2 Electroreduction

W Ren, X Tan, C Jia, A Krammer, Q Sun… - Angewandte …, 2022 - Wiley Online Library
Modulating the electronic structure of atomically dispersed active sites is promising to boost
catalytic activity but is challenging to achieve. Here we show a cooperative Ni single‐atom …

Diversity and evolution of methane-related pathways in archaea

PS Garcia, S Gribaldo, G Borrel - Annual Review of Microbiology, 2022 - annualreviews.org
Methane is one of the most important greenhouse gases on Earth and holds an important
place in the global carbon cycle. Archaea are the only organisms that use methanogenesis …

Industrial biomanufacturing: the future of chemical production

JM Clomburg, AM Crumbley, R Gonzalez - Science, 2017 - science.org
BACKGROUND Environmental, geopolitical, and economic factors are reshaping our view
of global energy and manufacturing demands. Addressing these challenges may require a …

Elucidating the roles of electric fields in catalysis: a perspective

F Che, JT Gray, S Ha, N Kruse, SL Scott… - ACS …, 2018 - ACS Publications
This Perspective illustrates how the presence of internal and external electric fields can
affect catalytic activity and selectivity, with a focus on heterogeneous catalysts. Specifically …

Atomically Dispersed Nickel(I) on an Alloy‐Encapsulated Nitrogen‐Doped Carbon Nanotube Array for High‐Performance Electrochemical CO2 Reduction Reaction

T Zhang, X Han, H Yang, A Han, E Hu… - Angewandte Chemie …, 2020 - Wiley Online Library
Single‐atom catalysts (SACs) show great promise for electrochemical CO2 reduction
reaction (CRR), but the low density of active sites and the poor electrical conduction and …