Technological innovations in photochemistry for organic synthesis: flow chemistry, high-throughput experimentation, scale-up, and photoelectrochemistry

L Buglioni, F Raymenants, A Slattery… - Chemical …, 2021 - ACS Publications
Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …

Electrocatalysis as an enabling technology for organic synthesis

LFT Novaes, J Liu, Y Shen, L Lu… - Chemical Society …, 2021 - pubs.rsc.org
Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …

Cyclic voltammetry and chronoamperometry: mechanistic tools for organic electrosynthesis

M Rafiee, DJ Abrams, L Cardinale, Z Goss… - Chemical Society …, 2024 - pubs.rsc.org
Electrochemical methods offer unique advantages for chemical synthesis, as the reaction
selectivity may be controlled by tuning the applied potential or current. Similarly, measuring …

Synthetic organic electrochemical methods since 2000: on the verge of a renaissance

M Yan, Y Kawamata, PS Baran - Chemical Reviews, 2017 - ACS Publications
Electrochemistry represents one of the most intimate ways of interacting with molecules. This
review discusses advances in synthetic organic electrochemistry since 2000. Enabling …

Electrochemical strategies for C–H functionalization and C–N bond formation

MD Kärkäs - Chemical Society Reviews, 2018 - pubs.rsc.org
Conventional methods for carrying out carbon–hydrogen functionalization and carbon–
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …

Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic …

JE Nutting, M Rafiee, SS Stahl - Chemical reviews, 2018 - ACS Publications
N-Oxyl compounds represent a diverse group of reagents that find widespread use as
catalysts for the selective oxidation of organic molecules in both laboratory and industrial …

Redox: Organic robust radicals and their polymers for energy conversion/storage devices

K Hatakeyama-Sato, K Oyaizu - Chemical Reviews, 2023 - ACS Publications
Persistent radicals can hold their unpaired electrons even under conditions where they
accumulate, leading to the unique characteristics of radical ensembles with open-shell …

Predictive and mechanistic multivariate linear regression models for reaction development

CB Santiago, JY Guo, MS Sigman - Chemical science, 2018 - pubs.rsc.org
Multivariate Linear Regression (MLR) models utilizing computationally-derived and
empirically-derived physical organic molecular descriptors are described in this review …

The development of multidimensional analysis tools for asymmetric catalysis and beyond

MS Sigman, KC Harper, EN Bess… - Accounts of chemical …, 2016 - ACS Publications
Conspectus In most modern organic chemistry reports, including many of ours, reaction
optimization schemes are typically presented to showcase how reaction conditions have …

Redox catalysis facilitates lignin depolymerization

I Bosque, G Magallanes, M Rigoulet… - ACS central …, 2017 - ACS Publications
Lignin is a recalcitrant and underexploited natural feedstock for aromatic commodity
chemicals, and its degradation generally requires the use of high temperatures and harsh …