Tracking excited state decay mechanisms of pyrimidine nucleosides in real time

R Borrego-Varillas, A Nenov, P Kabaciński… - Nature …, 2021 - nature.com
DNA owes its remarkable photostability to its building blocks—the nucleosides—that
efficiently dissipate the energy acquired upon ultraviolet light absorption. The mechanism …

UV-Light-Induced Vibrational Coherences: The Key to Understand Kasha Rule Violation in trans-Azobenzene

A Nenov, R Borrego-Varillas, A Oriana… - The journal of …, 2018 - ACS Publications
We combine sub-20 fs transient absorption spectroscopy with state-of-the-art computations
to study the ultrafast photoinduced dynamics of trans-azobenzene (AB). We are able to …

Ultraviolet pulse compression via cross-phase modulation in a hollow-core fiber

Y Jiang, JP Messerschmidt, F Scheiba, I Tyulnev… - Optica, 2024 - opg.optica.org
The generation of few-femtosecond pulses with high energy and tunable spectrum in the
ultraviolet region is an ongoing challenge in ultrafast optics. Harnessing the cross-phase …

Observation of the sub-100 femtosecond population of a dark state in a thiobase mediating intersystem crossing

R Borrego-Varillas, DC Teles-Ferreira… - Journal of the …, 2018 - ACS Publications
We combined sub-30 fs broadband transient absorption spectroscopy in the ultraviolet with
state-of-the-art quantum mechanics/molecular mechanics simulations to study the ultrafast …

Strongly Coupled Coherent Phonons in Single-Layer MoS2

C Trovatello, HPC Miranda, A Molina-Sanchez… - ACS …, 2020 - ACS Publications
We present a transient absorption setup combining broadband detection over the visible–
UV range with high temporal resolution (∼ 20 fs) which is ideally suited to trigger and detect …

Ultraviolet transient absorption spectrometer with sub-20-fs time resolution

R Borrego-Varillas, L Ganzer, G Cerullo, C Manzoni - Applied Sciences, 2018 - mdpi.com
We describe a transient absorption (TA) spectroscopy system in the ultraviolet (UV) spectral
range, for the study of the ultrafast optical response of biomolecules. After reviewing the …

Optical parametric amplification of sub-cycle shortwave infrared pulses

YC Lin, Y Nabekawa, K Midorikawa - Nature communications, 2020 - nature.com
Few–cycle short–wave infrared (SWIR) pulses are useful tools for research on strong–field
physics and nonlinear optics. Here we demonstrate the amplification of sub–cycle pulses in …

Engineering the vibrational coherence of vision into a synthetic molecular device

M Gueye, M Manathunga, D Agathangelou… - Nature …, 2018 - nature.com
The light-induced double-bond isomerization of the visual pigment rhodopsin operates a
molecular-level optomechanical energy transduction, which triggers a crucial protein …

A unified experimental/theoretical description of the ultrafast photophysics of single and double thionated uracils

DC Teles‐Ferreira, I Conti… - … A European Journal, 2020 - Wiley Online Library
Photoinduced processes in thiouracil derivatives have lately attracted considerable attention
due to their suitability for innovative biological and pharmacological applications. Here, sub …

Real-time observation of sub-100-fs charge and energy transfer processes in DNA dinucleotides

V Petropoulos, L Martinez-Fernandez, L Uboldi… - Chemical …, 2024 - pubs.rsc.org
Using as showcase the DNA dinucleotide 5′-dTpdG-3′, in which the thymine (T) is
located at the 5′ end with respect to the guanine (G), we study the photoinduced electronic …