Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds

S Rej, Y Ano, N Chatani - Chemical reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Characterization and Reactivity of Copper (II) and Copper (III) σ-Aryl Intermediates in Aminoquinoline-Directed C–H Functionalization

IM Blythe, J Xu, JS Fernandez Odell… - Journal of the …, 2023 - ACS Publications
Over the past decade, numerous reports have focused on the development and applications
of Cu-mediated C–H functionalization reactions; however, to date, little is known about the …

Recent advances and prospects in nickel-catalyzed C–H activation

NA Harry, S Saranya, SM Ujwaldev… - Catalysis Science & …, 2019 - pubs.rsc.org
Nickel-catalyzed C–H activation has become a predominant and ubiquitous research area
in organic chemistry. Direct functionalization of inert C–H bonds to create functionally …

Removal and modification of directing groups used in metal-catalyzed C–H functionalization: the magical step of conversion into 'conventional'functional groups

RL Carvalho, RG Almeida, K Murali… - Organic & …, 2021 - pubs.rsc.org
Over the past few decades, regioselective catalytic C–H functionalization has provided an
attractive tool for unique retrosynthetic disconnections. The advancement of the directing …

Rapid construction of tetralin, chromane, and indane motifs via cyclative C–H/C–H coupling: four-step total synthesis of (±)-russujaponol F

Z Zhuang, AN Herron, S Liu, JQ Yu - Journal of the American …, 2021 - ACS Publications
The development of practical C–H/C–H coupling reactions remains a challenging yet
appealing synthetic venture because it circumvents the need to prefunctionalize both …

Cross-dehydrogenative coupling of unactivated alkanes

J Li, CY Huang, CJ Li - Trends in Chemistry, 2022 - cell.com
Chemists have been seeking simple and efficient methods to form C–C bonds, which are
paramount in organic synthesis, advanced materials, and life science. Towards this goal …

Recent progress in the oxidative coupling of unactivated Csp 3–H bonds with other C–H bonds

Y Liao, F Liu, Z Shi - Chemical Communications, 2021 - pubs.rsc.org
The oxidative coupling between two carbon–hydrogen (C–H) bonds offers the most
straightforward pathway to construct C–C bonds from hydrocarbons without pre …

Understanding Ni(II)-Mediated C(sp3)–H Activation: Tertiary Ureas as Model Substrates

DD Beattie, AC Grunwald, T Perse… - Journal of the …, 2018 - ACS Publications
We report a mechanistic study of C (sp3)–H bond activation mediated by nickel.
Cyclometalated Ni (II) ureate [(PEt3) Ni (κ3-C, N, N-(C H2) N (Cy)(CO) N ((N)-quinolin-8-yl))] …