Base-Mediated Visible-Light-Driven C–H Arylation of Quinoxalin-2(1H)-Ones in Ethanol

Y Pan, L Wang, Y Shi, G Huang, X Bu… - The Journal of …, 2024 - ACS Publications
Prior methods for visible-light-driven C–H arylation of quinoxalin-2 (1 H)-ones relied on
external photocatalysts. Herein, we report a photocatalyst-free approach for this arylation. In …

Electrochemical Regioselective C(sp2)–H Bond Chalcogenation of Pyrazolo[1,5-a]pyrimidines via Radical Cross-Coupling at Room Temperature

AS Chillal, RT Bhawale, S Sharma… - The Journal of Organic …, 2024 - ACS Publications
Herein, we disclose an electrochemical approach for the C (sp2)–H chalcogenation of
pyrazolo [1, 5-a] pyrimidines. This technique offers an oxidant and catalyst-free protocol for …

Catalytic Photoredox C–H Arylation of 4-Oxo-4H-pyrido[1,2-a]pyrimidine-3-diazonium Tetrafluoroborates and Related Heteroaryl Diazonium Salts

K Antolinc, H Brodnik, U Grošelj… - The Journal of …, 2023 - ACS Publications
Irradiation of mixtures of title diazonium salts and heteroarenes with green light (510 nm) in
the presence of eosin Y disodium salt (EY-Na 2) as a photocatalyst furnished the …

Visible‐Light Induced Ag‐Palladacycle‐Complex‐Mediated Regioselective C− H Arylation

RT Bhawale, AS Chillal, S Ghosh… - … Synthesis & Catalysis, 2024 - Wiley Online Library
A visible‐light‐induced, external photocatalyst‐free, site‐selective C− H arylation of 4H‐
pyrido [1, 2‐a] pyrimidin‐4‐ones and various 2‐aryl heteroarenes has been developed to …

Supporting Electrolyte‐Free Electrochemical Oxidative C− H Sulfonylation and Thiocyanation of Fused Pyrimidin‐4‐Ones in an All‐Green Electrolytic System

S Biswas, S Ghosh, I Das - Chemistry–A European Journal, 2024 - Wiley Online Library
An electrooxidative C− H functionalization is a widely accepted route to obtain sulfur‐
containing arenes and heteroarenes. However, this process often involves using non …

Micelle-Assisted C(sp2)–H Functionalization for C–Se and C–X Bond Formation in the Aqueous Medium

AS Chillal, C Maurya, UA Kshirsagar - Langmuir, 2024 - ACS Publications
An environmentally sustainable, versatile, and cost-effective approach for C–Se and C–X
(X= I, Br, and Cl) bond formation through C–H functionalization assisted by micellar catalysis …

Recent Advances of 3-Hetero-substituted 4H-pyrido [1, 2-a] pyrimidin-4-one: A Review

SK Mandal - Current Green Chemistry, 2025 - benthamdirect.com
Late-stage functionalization of pyrido [1, 2-a] pyrimidin-4-one at pyrimidine ring structure is
crucial to design pharmaceuticals, agrochemicals and materials for sustainable …

Eosin Y Catalyzed Photochemical Synthesis of Arylated Phenothiazones

B Nagar, SK Yadav, N Karmodak, BB Dhar - ACS omega, 2024 - ACS Publications
In the presence of Eosin Y (EY), the synthesis of substituted phenothiazones was carried out
efficiently using various substituted 2-aminothiophenol, diazonium salts, and 1, 4 …

Visible-light-promoted Meerwein 3, 4-diarylation of maleimides with electron-deficient diazonium salts

AD Kharlamova, AS Abel, VE Gontcharenko, AD Averin… - Tetrahedron, 2024 - Elsevier
Diarylmaleimides are widely explored as structural fragments of natural products, bioactive
substances and components of luminescent materials. The reaction of aryl diazonium salts …

Visible‐Light‐Enabled Regioselective C− H alkylation and alkenylation of 2‐Aryl Heterocycles using Dual Catalysis

RT Bhawale, AS Chillal… - Advanced Synthesis & …, 2024 - Wiley Online Library
Visible light‐induced site‐selective C− H alkylation and alkenylation of 2‐aryl heteroarenes
with maleimides at room temperature via dual catalysis in an aqueous medium has been …