Conspectus Boron is an interesting element with unusual polymorphism. While three- dimensional (3D) structural motifs are prevalent in bulk boron, atomic boron clusters are …
LS Wang - International Reviews in Physical Chemistry, 2016 - Taylor & Francis
Photoelectron spectroscopy (PES) in combination with computational chemistry has been used systematically over the past decade to elucidate the structures and chemical bonding …
WL Li, Q Chen, WJ Tian, H Bai, YF Zhao… - Journal of the …, 2014 - ACS Publications
Elemental boron is electron-deficient and cannot form graphene-like structures. Instead, triangular boron lattices with hexagonal vacancies have been predicted to be stable. A …
LM Yang, E Ganz, Z Chen, ZX Wang… - Angewandte Chemie …, 2015 - Wiley Online Library
The idea of planar tetracoordinate carbon (ptC) was considered implausible for a hundred years after 1874. Examples of ptC were then predicted computationally and realized …
We have investigated the structural and electronic properties of the B 17− and B 18− clusters using photoelectron spectroscopy (PES) and ab initio calculations. The adiabatic electron …
C Romanescu, TR Galeev, WL Li… - Accounts of chemical …, 2013 - ACS Publications
Atomic clusters have intermediate properties between that of individual atoms and bulk solids, which provide fertile ground for the discovery of new molecules and novel chemical …
Boron, as a unique element nearest to carbon in the periodic table, has been predicted to form many distinctive two‐dimensional (2D) structures that significantly differ from other well …
Aromaticity is indispensable for explaining a variety of chemical behaviors, including reactivity, structural features, relative energetic stabilities, and spectroscopic properties …
AP Sergeeva, ZA Piazza, C Romanescu… - Journal of the …, 2012 - ACS Publications
Clusters of boron atoms exhibit intriguing size-dependent structures and chemical bonding that are different from bulk boron and may lead to new boron-based nanostructures. We …