Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Azine‐containing biaryls are ubiquitous scaffolds in many areas of chemistry, and efficient
methods for their synthesis are continually desired. Pyridine rings are prominent amongst …

Conspectus Since the advent of metal-catalyzed cross-coupling technology more than 40
years ago, the field has grown to be ever-increasingly enabling, yet the employed coupling …

This report describes the chemoselective coupling of polyfluoroarenes with aryl germanes in
the presence of aromatic C–I, C–Br, C–Cl, C–OTf, and C–SiMe3 groups, as well as …

Dinuclear PdI complexes have found widespread applications as diverse catalysts for a
multitude of transformations. Initially their ability to function as pre‐catalysts for low …

Within the sphere of traditional Pd0/PdII cross coupling reactions, organogermanes have
been historically outperformed both in terms of scope and reactivity by more conventional …

Nitroaromatic compounds represent one of the essential classes of molecules that are
widely used as feedstock for the synthesis of intermediates, the preparation of nitro‐derived …

Site-selective dihalogenated heteroarene cross-coupling with organometallic reagents
usually occurs at the halogen proximal to the heteroatom, enabled by intrinsic relative …

A catalytic approach of synthesizing the cis-selective saturated carbo-and heterocyclic
germanium compounds (3D framework) is reported via the hydrogenation of readily …

To meet the need for a rapid, streamlined, and potentially automatable molecule synthesis,
modular coupling approaches are highly desired. While the diversification of aromatic …