Combustion chemistry of aromatic hydrocarbons

H Jin, W Yuan, W Li, J Yang, Z Zhou, L Zhao… - Progress in Energy and …, 2023 - Elsevier
Aromatic hydrocarbons are important components of petroleum-based transportation fuels,
biomass, coal, and solid waste, etc. The reaction kinetics of aromatic hydrocarbons largely …

An aromatic universe–A physical chemistry perspective

RI Kaiser, N Hansen - The Journal of Physical Chemistry A, 2021 - ACS Publications
This Perspective presents recent advances in our knowledge of the fundamental elementary
mechanisms involved in the low-and high-temperature molecular mass growth processes to …

Photoelectron photoion coincidence spectroscopy provides mechanistic insights in fuel synthesis and conversion

P Hemberger, A Bodi, T Bierkandt, M Köhler… - Energy & …, 2021 - ACS Publications
Clean combustion, ie, the reduction of NOx and soot emissions, and carbon neutrality,
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …

Fully fused boron-doped polycyclic aromatic hydrocarbons: their synthesis, structure–property relationships, and self-assembly behavior in aqueous media

H Narita, H Choi, M Ito, N Ando, S Ogi… - Chemical Science, 2022 - pubs.rsc.org
Planarized triarylboranes are attracting increasing attention not only as models of boron-
doped graphenes, but also as promising materials for organic optoelectronics. In particular …

Role of Acetylene in the Chemical Evolution of Carbon Complexity

EO Pentsak, MS Murga… - ACS Earth and Space …, 2024 - ACS Publications
Acetylene, among the multitude of organic molecules discovered in space, plays a distinct
role in the genesis of organic matter. Characterized by its unique balance of stability and …

Gas-phase preparation of azulene (C 10 H 8) and naphthalene (C 10 H 8) via the reaction of the resonantly stabilized fulvenallenyl (C 7 H 5˙) and propargyl (C 3 H 3˙) …

W Li, J Yang, L Zhao, D Couch, M San Marchi… - Chemical …, 2023 - pubs.rsc.org
Synthetic routes to the 10π Hückel aromatic azulene (C10H8) molecule, the simplest
polycyclic aromatic hydrocarbon carrying an adjacent five-and seven-membered ring, have …

Spiers Memorial Lecture: New directions in molecular scattering

GC Schatz, AM Wodtke, X Yang - Faraday Discussions, 2024 - pubs.rsc.org
The field of Molecular Scattering is reviewed as it pertains to gas-gas as well as gas-surface
chemical reaction dynamics. We emphasize the importance of collaboration of experiment …

Bay capping via acetylene addition to polycyclic aromatic hydrocarbons: Mechanism and kinetics

LB Tuli, AM Mebel, M Frenklach - Proceedings of the Combustion Institute, 2023 - Elsevier
The bay-capping mechanism on PAH armchair edges and the kinetics of acetylene addition
to 6–6–5 and 5–6–5 bays have been explored by ab initio/RRKM-ME calculations. The bays …

Radical–radical reactions in molecular weight growth: The phenyl+ propargyl reaction

TM Selby, F Goulay, S Soorkia, A Ray… - The Journal of …, 2023 - ACS Publications
The mechanism for hydrocarbon ring growth in sooting environments is still the subject of
considerable debate. The reaction of phenyl radical (C6H5) with propargyl radical …

Low-temperature formation of pyridine and (iso) quinoline via neutral–neutral reactions

Z Yang, C He, SJ Goettl, AM Mebel, PFG Velloso… - Nature …, 2024 - nature.com
Aromatic molecules represent fundamental building blocks in prebiotic chemistry and are
contemplated as vital precursors to DNA and RNA nitrogen bases. However, despite the …