Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …

The addition of X3Si–H or X2B–H (X= H, OR or R) across a C–C multiple bond is a well-
established method for incorporating silane or borane groups, respectively, into …

The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

A mild, chemo-and site-selective catalytic protocol that allows for incorporating an alkylboron
fragment into unactivated olefins is described. The use of internal olefins enables C–C bond …

Multi (boronate) esters have been attracting increasing attention as versatile building blocks
for the succinct and precise synthesis of complex molecules. However, there are a limited …

We report a general protocol for the convergent synthesis of 1, 4-dicarbonyl Z-alkenes form
alkynes using α-diazo sulfonium triflate and water. The C═ O, C═ C, and C–H bonds are …

The aluminum-catalyzed hydroboration of alkenes with HBpin is reported using simple
commercially available aluminum hydride precatalysts [LiAlH4 or sodium bis (2 …

A neighboring boronate group in the substrate provides a dramatic rate acceleration in
transmetalation to copper and thereby enables organoboronic esters to participate in …

This review discusses recent advances in the chemistry of saturated boronic acids,
boronates, and trifluoroborates. Applications of the title compounds in the design of boron …

Recent years have witnessed the growing interest in the remote functionalization of alkenes
for it offers a strategy to activate the challenging C–H bonds distant from the initiation point …