3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Oxidative C–H/C–H coupling reactions between two (hetero) arenes

Y Yang, J Lan, J You - Chemical reviews, 2017 - ACS Publications
Transition metal-mediated C–H bond activation and functionalization represent one of the
most straightforward and powerful tools in modern organic synthetic chemistry. Bi (hetero) …

C–H functionalization of azines

K Murakami, S Yamada, T Kaneda, K Itami - Chemical Reviews, 2017 - ACS Publications
Azines, which are six-membered aromatic compounds containing one or more nitrogen
atoms, serve as ubiquitous structural cores of aromatic species with important applications in …

Aerobic copper-catalyzed organic reactions

SE Allen, RR Walvoord, R Padilla-Salinas… - Chemical …, 2013 - ACS Publications
The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

SH Cho, JY Kim, J Kwak, S Chang - Chemical Society Reviews, 2011 - pubs.rsc.org
The direct functionalization of heterocyclic compounds has emerged as one of the most
important topics in the field of metal-catalyzed C–H bond activation due to the fact that …

Copper‐Catalyzed Aerobic Oxidative C H Functionalizations: Trends and Mechanistic Insights

AE Wendlandt, AM Suess… - Angewandte Chemie …, 2011 - Wiley Online Library
The selective oxidation of C H bonds and the use of O2 as a stoichiometric oxidant
represent two prominent challenges in organic chemistry. Copper (II) is a versatile oxidant …

Bond formations between two nucleophiles: transition metal catalyzed oxidative cross-coupling reactions

C Liu, H Zhang, W Shi, A Lei - Chemical Reviews, 2011 - ACS Publications
In chemistry, a nucleophile is a molecule or ion with a lone pair of electrons. It donates both
bonding electrons to its reaction partner (the electrophile) when forming a chemical bond. 1 …

Developing ligands for palladium (II)-catalyzed C–H functionalization: intimate dialogue between ligand and substrate

KM Engle, JQ Yu - The Journal of organic chemistry, 2013 - ACS Publications
Homogeneous transition-metal-catalyzed reactions are indispensable to all facets of modern
chemical synthesis. It is thus difficult to imagine that for much of the early 20th century, the …

Copper-Promoted Sulfenylation of sp2 C–H Bonds

LD Tran, I Popov, O Daugulis - Journal of the American Chemical …, 2012 - ACS Publications
An auxiliary-assisted, copper catalyzed or promoted sulfenylation of benzoic acid derivative
β-C–H bonds and benzylamine derivative γ-C–H bonds has been developed. The method …

Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

Z Shi, C Zhang, C Tang, N Jiao - Chemical Society Reviews, 2012 - pubs.rsc.org
For green and sustainable chemistry, molecular oxygen is considered as an ideal oxidant
due to its natural, inexpensive, and environmentally friendly characteristics, and therefore …