Mn-, Fe-, and Co-catalyzed radical hydrofunctionalizations of olefins

SWM Crossley, C Obradors, RM Martinez… - Chemical …, 2016 - ACS Publications
Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas
reactions to form a wide range of Markovnikov-selective olefin radical …

The chemistry of heterocycles in the 21st century

VN Charushin, EV Verbitskiy, ON Chupakhin… - Uspekhi Khimii, 2024 - mathnet.ru
The chemistry of heterocyclic compounds has traditionally been and remains a bright area of
chemical science in Russia. This is due to the fact that many heterocycles find the widest …

Electrocatalysis with molecular transition-metal complexes for reductive organic synthesis

N Kaeffer, W Leitner - JACS Au, 2022 - ACS Publications
Electrocatalysis enables the formation or cleavage of chemical bonds by a genuine use of
electrons or holes from an electrical energy input. As such, electrocatalysis offers resource …

Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches

RC e Silva, LO da Silva… - Beilstein Journal of …, 2020 - beilstein-journals.org
In this review we present relevant and recent applications of porphyrin derivatives as
photocatalysts in organic synthesis, involving both single electron transfer (SET) and energy …

[HTML][HTML] Understanding and exploiting long-lived near-infrared emission of a molecular ruby

S Otto, M Dorn, C Förster, M Bauer, M Seitz… - Coordination Chemistry …, 2018 - Elsevier
Enabling strong and long-lived NIR emission from complexes with earth-abundant metal
ions is exemplified by embedding chromium (III) in a very strong ligand field yielding the …

Inverse α-Effect as the Ariadne's Thread on the Way to Tricyclic Aminoperoxides: Avoiding Thermodynamic Traps in the Labyrinth of Possibilities

IA Yaremenko, YY Belyakova, PS Radulov… - Journal of the …, 2022 - ACS Publications
Stable tricyclic aminoperoxides can be selectively assembled via a catalyst-free three-
component condensation of β, δ′-triketones, H2O2, and an NH-group source such as …

Stereoelectronic effects in the formation of 5-and 6-membered rings: the role of Baldwin's rules

CD Johnson - Accounts of chemical research, 1993 - ACS Publications
The demonstration by Dunitz and hisco-workers1 of favored trajectories for the approach of
one reactant molecule toward another led to the formulation of rules governing the ease of …

Peroxides in metal complex catalysis

Z Ma, KT Mahmudov, VA Aliyeva, AV Gurbanov… - Coordination Chemistry …, 2021 - Elsevier
Peroxides form an important class of chemicals in which two oxygen atoms are linked
together by a single covalent bond (R− O− O− R, R= H, SO 3 K, alkyl, etc.), with a wide range …

Photo‐Chromium: Sensitizer for Visible‐Light‐Induced Oxidative C− H Bond Functionalization—Electron or Energy Transfer?

S Otto, AM Nauth, E Ermilov, N Scholz… - …, 2017 - Wiley Online Library
The chromium (III) sensitizer [Cr (ddpd) 2] 3+(ddpd= N, N′‐dimethyl‐N, N′‐dipyridine‐2‐
ylpyridine‐2, 6‐diamine), based on an earth‐abundant metal centre, possesses a unique …

Upconversion of reductants

MA Syroeshkin, F Kuriakose… - Angewandte Chemie …, 2019 - Wiley Online Library
The many applications of photon upconversion—conversion of low‐energy photons into
high‐energy photons—raises the question of the possibility of “electron upconversion”. In …