Sixty years of the van der Waals and Platteeuw model for clathrate hydrates—A critical review from its statistical thermodynamic basis to its extensions and …

FDA Medeiros, ISV Segtovich, FW Tavares… - Chemical …, 2020 - ACS Publications
In light of the 60-year anniversary of the publishing of “Clathrate Solutions” by van der Waals
and Platteeuw in 2019, we present a critical review of the famed solid solution model first …

Physical chemistry and technological applications of gas hydrates: topical aspects

AY Manakov, AS Stoporev - Russian Chemical Reviews, 2021 - iopscience.iop.org
The review considers the research and engineering works in selected fields of the physical
chemistry of gas hydrates and gas hydrate technologies, mainly performed over the last 10 …

Searching for synergy between alcohol and salt to produce more potent and environmentally benign gas hydrate inhibitors

AP Semenov, RI Mendgaziev, VA Istomin… - Chemical Engineering …, 2024 - Elsevier
Gas hydrates formation is a primary complication in the oil and gas industry. The most
universal gas hydrate prevention agents are thermodynamic inhibitors. The most prominent …

Liquid layer generators for excellent icephobicity at extremely low temperatures

F Wang, S Xiao, Y Zhuo, W Ding, J He, Z Zhang - Materials Horizons, 2019 - pubs.rsc.org
Promising progress in the field of icephobicity has been made in the recent years. However,
a majority of the reported icephobic surfaces rely on static mechanisms, and they maintain …

Hydrogen-bonding alcohol-water interactions in binary ethanol, 1-propanol, and 2-propanol+ methane structure II clathrate hydrates

S Alavi, S Takeya, R Ohmura, TK Woo… - The Journal of chemical …, 2010 - pubs.aip.org
The small alcohols ethanol, 1-propanol, and 2-propanol are miscible in water, form strong
hydrogen bonds with water molecules, and are usually known as inhibitors for clathrate …

Effect of guest–host hydrogen bonding on the structures and properties of clathrate hydrates

S Alavi, K Udachin… - Chemistry–A European …, 2010 - Wiley Online Library
To provide improved understanding of guest–host interactions in clathrate hydrates, we
present some correlations between guest chemical structures and observations on the …

Gas hydrate phase equilibrium in the presence of ethylene glycol or methanol aqueous solution

AH Mohammadi, D Richon - Industrial & engineering chemistry …, 2010 - ACS Publications
In this communication, experimental hydrate dissociation data for the ethane, carbon
dioxide, or hydrogen sulfide+ ethylene glycol+ water system are first reported at 0.1, 0.2 …

Universal correlation for gas hydrates suppression temperature of inhibited systems: III. salts and organic inhibitors

Y Hu, JH Sa, BR Lee, AK Sum - AIChE Journal, 2018 - Wiley Online Library
In Parts I and II, the Hu‐Lee‐Sum (HLS) correlation was developed and demonstrated to
have an inherent generality and simplicity to predict structures I and II gas hydrates …

Effect of alcohols and diols on PVCap-induced hydrate crystal growth patterns in methane systems

H Mozaffar, R Anderson, B Tohidi - Fluid Phase Equilibria, 2016 - Elsevier
Abstract Methanol (MeOH), mono-ethylene-glycol (MEG) and ethanol (EtOH) are the most
widely used thermodynamic hydrate inhibitors (THIs) for hydrate inhibition in hydrocarbon …

Experimental and computational investigation of hydrophilic monomeric substances as novel CO2 hydrate inhibitors and potential synergists

W Go, S Yun, D Lee, Y Seo - Energy, 2022 - Elsevier
CO 2 hydrate formation in the CO 2 transmission pipelines for ocean or geological
sequestration can result in pipeline blockage and rupture. Herein, monomeric substances …