Milestones and most recent advances in Corrole's Science and Technology

A Mahammed, Z Gross - Journal of the American Chemical …, 2023 - ACS Publications
The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …

Assessing intersystem crossing rates in donor-and/acceptor-functionalized corroles: A computational study

AM Tedy, R Ahmed, AK Manna - The Journal of Physical …, 2023 - ACS Publications
Small singlet–triplet gap (Δ ES–T) and large spin–orbit coupling (SOC) between the low-
lying excited spin singlet and triplet states greatly promote the intersystem crossing (ISC) …

Phosphorus Corroles: Tuning of their Photophysical and Redox Properties via Axial Ligation and Macrocycle Modification

W Sinha, N Fridman, A Mahammed… - Israel Journal of …, 2023 - Wiley Online Library
Given the increased interest in phosphorus corroles for many applications, we now report
how their photophysical variables and redox potentials may be tuned. This was performed …

Phenoxide coordination to Fe (III) tetraphenylporphyrin: Exploring antibacterial and electrocatalytic HER activity

M Patra, TK Das, A Saha, T Das, A Patra, S Garai… - Inorganica Chimica …, 2024 - Elsevier
Herein, we report synthesis, solid and solution state structure as well as properties of three
five coordinate (unsubstituted, 4-NO 2 substituted and 2, 4, 6 trinitro substituted) phenoxide …

On-Surface Synthesis of Novel Macrocyclic Nanostructures via C–C Coupling Assisted by Coordination Pocket Templates

H Xu - 2024 - mediatum.ub.tum.de
We demonstrate the on-surface synthesis and characterization of novel macrocyclic
nanostructures characterized by scanning probe microscopy. Intermolecular C–C coupling …