Recent developments in the stereoselective synthesis of polysubstituted cyclopropanes
nowadays allow chemists to easily access these strained rings with high diastereo-and …

Ring-opening transformations of donor–acceptor cyclopropanes (DAC) with carbon-
centered nucleophiles is a simple, straight-forward approach to 1, 3-bifunctional compounds …

Abstract The reaction of bicyclo [1.1. 0] butyl pinacol boronic ester (BCB‐Bpin) with
nucleophiles has been studied. Unlike BCBs bearing electron‐withdrawing groups, which …

The Cu-catalyzed 1, 4-protosilylation and protoborylation of trifluoromethyl-substituted
conjugated enynes were developed to access functionalized homoallenylsilanes and …

Herein, we present the formation of acyclic frameworks bearing two consecutive
stereocenters of either tertiary or quaternary nature starting from easily accessible …

Yb (OTf) 3 catalyzed mild and regioselective ring-opening 1, 3-aminothiolation of donor–
acceptor (D–A) cyclopropanes using sulfenamides has been demonstrated. The insertion of …

Abstract A 1, 3‐aminothiolation was realized by reacting 2‐substituted cyclopropane 1, 1‐
dicarboxylates with sulfonamides and N‐(arylthio) succinimides. Under Sn (OTf) 2 catalysis …

Alkyl pinacol boronic esters have been routinely used for the synthesis of complex target
molecules or high-value chemicals due to their non-toxicity, stability and commercial …

Since the discovery of the pioneering cross-coupling name reactions in the 1970s, cross-
coupling involving organolithium reagents (Murahashi coupling) has been neglected for …

Cyclopropanes are unique three-member rings whose unusual bonding and inherent ring
strain make them valuable building blocks in modern organic synthesis. In this work, a Pd …