Coordination complexes of bis (amido) cyclodiphosph (III/V and V/V) azane imides and chalcogenides
GG Briand, T Chivers, M Krahn - Coordination Chemistry Reviews, 2002 - Elsevier
Metaphosphates with imido and chalcogenido substituents attached to a central phosphorus
(V) center form ambidentate dimeric dianions that are potential components of metal …
(V) center form ambidentate dimeric dianions that are potential components of metal …
Activation of small molecules by phosphorus biradicaloids
A Hinz, R Kuzora, U Rosenthal… - … –A European Journal, 2014 - Wiley Online Library
The reactivity of biradicaloid [P (μ‐NTer)] 2 was employed to activate small molecules
bearing single, double, and triple bonds. Addition of chalcogens (O2, S8, Sex and Tex) led …
bearing single, double, and triple bonds. Addition of chalcogens (O2, S8, Sex and Tex) led …
Preparation of the [(DippNP)2(P4)2]2+-Dication by the Reaction of [DippNPCl]2 and a Lewis Acid with P4
MH Holthausen, JJ Weigand - Journal of the American Chemical …, 2009 - ACS Publications
The controlled activation of white phosphorus, P4, provides a key entry point into many
aspects of phosphorus chemistry. The activation and functionalization of P4 by N …
aspects of phosphorus chemistry. The activation and functionalization of P4 by N …
Synthesis and structural characterization of a new class of macrocycles based on a cyclodiphosphazane skeleton
P Kommana, KC Kumara Swamy - Inorganic Chemistry, 2000 - ACS Publications
The novel macrocyclic compounds {(OCH2CMe2CH2O)[(S) PN-t-Bu] 2} 2 (4) and
{(OCH2CMe2CH2O)[P (Nt-Bu) 2P (1, 2-O2C6Cl4)]} 2⊙ 3C6H5CH3 (5⊙ 3C6H5CH3) based …
{(OCH2CMe2CH2O)[P (Nt-Bu) 2P (1, 2-O2C6Cl4)]} 2⊙ 3C6H5CH3 (5⊙ 3C6H5CH3) based …
Synthesis and Hydrolytic Studies on the Air-Stable [(4-CN-PhO)(E)P(μ-NtBu)]2 (E = O, S, and Se) Cyclodiphosphazanes
YX Shi, RZ Liang, KA Martin, N Weston… - Inorganic …, 2015 - ACS Publications
Reaction of 4-CN-PhOH with [ClP (μ-N t Bu)] 2 (1)(2: 1 ratio) in the presence of Et3N
produced the functionalized cyclodiphosph (III/III) azane [(4-CN-PhO) P (μ-N t Bu)] 2 (2) …
produced the functionalized cyclodiphosph (III/III) azane [(4-CN-PhO) P (μ-N t Bu)] 2 (2) …
Cage Silaphosphanes with a P→ Si dative bond
VF Sidorkin, EP Doronina - Organometallics, 2009 - ACS Publications
The design of the cage silaphosphanes XSi (− L−) 3P (X= Me (a), F (b); L= YCH2Z (4− 19),
YC6H4 (20− 23), C6H4Z (24− 27), C10H6 (28), YCH2CH2Z (29-37), YC6H4Z (38− 46); Y …
YC6H4 (20− 23), C6H4Z (24− 27), C10H6 (28), YCH2CH2Z (29-37), YC6H4Z (38− 46); Y …
Steric C–N bond activation on the dimeric macrocycle [{P (μ-NR)} 2 (μ-NR)] 2
YX Shi, RZ Liang, KA Martin, DG Star, J Díaz… - Chemical …, 2015 - pubs.rsc.org
Dimeric cyclophosphazanes [{P (μ-NR)} 2 (μ-NR)] 2 [R= tBu (1) and iPr (3)] were oxidized
with elemental selenium. During these reactions an unexpected C–N bond cleavage and N …
with elemental selenium. During these reactions an unexpected C–N bond cleavage and N …
Aqueous Chemistry of Chlorocyclophosphazenes: Phosphates {PO2}, Phosphamides {P(O)NHR}, and the first Phosphites {PHO} and Pyrophosphates {(PO)2O} of …
J Ledger, R Boomishankar, A Steiner - Inorganic chemistry, 2010 - ACS Publications
Cyclotriphosphazenes have been functionalized with various oxo-groups at one of the ring
phosphorus atoms. Starting from geminal dichlorides (A) which are equipped with amino …
phosphorus atoms. Starting from geminal dichlorides (A) which are equipped with amino …
Cyclodiphosph (III) azane chemistry–Ylides from the reaction of [(RNH) PN (t-Bu)] 2 [R= t-Bu, i-Pr] with dimethyl maleate and chiral ansa-type derivatives from reaction …
KCK Swamy, G Gangadhararao, V Srinivas… - Inorganica Chimica …, 2011 - Elsevier
Use of a simple inorganic ring system with the cyclodiphosph (III) azane skeleton [eg [(RNH)
PN (t-Bu)] 2 [R= t-Bu (7), i-Pr (8)] to probe some of the intermediates proposed in phosphine …
PN (t-Bu)] 2 [R= t-Bu (7), i-Pr (8)] to probe some of the intermediates proposed in phosphine …
Synthesis and Structures of New Oxidation/ Cycloaddition Products of λ3‐Cyclodiphosphazanes
KP Kumar, M Chakravarty… - … für anorganische und …, 2004 - Wiley Online Library
Reaction of the cyclodiphosphazane [(OC4H8N) P (μ‐N‐t‐Bu) 2P (HN‐t‐Bu)](1) with an
equimolar quantity of diisopropyl azodicarboxylate afforded the phosphinimine product …
equimolar quantity of diisopropyl azodicarboxylate afforded the phosphinimine product …