H8[PV5Mo7O40] – A Unique Polyoxometalate for Acid and RedOx Catalysis: Synthesis, Characterization, and Modern Applications in Green Chemical Processes

JC Raabe, MJ Poller, D Voß, J Albert - ChemSusChem, 2023 - Wiley Online Library
Polyoxometalates (POMs) are a fascinating group of anionic metal‐oxide clusters with a
broad variety of structural properties and several catalytic applications, especially in the …

Comparative Spectroscopic and Electrochemical Study of V (V)-Substituted Keggin-Type Phosphomolybdates and-Tungstates

JC Raabe, J Aceituno Cruz, J Albert, MJ Poller - Inorganics, 2023 - mdpi.com
Vanadium-substituted Keggin-type heteropolyanions have been studied for a wide variety of
applications, ranging from catalysis to antiviral/antimicrobial agents. While the V-substituted …

An inorganic–organic hybrid material based on a Keggin‐type polyoxometalate@Dysprosium as an effective and green catalyst in the synthesis of 2‐amino‐4H …

S Hosseinzadeh‐Baghan, M Mirzaei… - Applied …, 2020 - Wiley Online Library
A novel inorganic–organic hybrid,[Dy4 (PDA) 4 (H2O) 11 (SiMo12O40)]· 7H2O denoted as
(POM@ Dy‐PDA), based on a lanthanide cluster, a Keggin‐type polyoxomolybdate, and …

Structure, stability, and electronic interactions of polyoxometalates on functionalized graphene sheets

JP Tessonnier, S Goubert-Renaudin, S Alia, Y Yan… - Langmuir, 2013 - ACS Publications
Polyoxometalates (H3PMo12O40, H3PW12O40, H4PMo11VO40) supported on oxygen-and
alkyl-functionalized graphene sheets were investigated. Discrete molecular species were …

Vanadium-doped sodium phosphomolybdate salts as catalysts in the terpene alcohols oxidation with hydrogen peroxide

CB Vilanculo, MJ da Silva, AA Rodrigues, SO Ferreira… - RSC …, 2021 - pubs.rsc.org
In this work, we have explored the catalytic activity of Keggin-type heteropolyanions PMo12−
nVnO40 (3+ n)−(n= 0, 1, 2, or 3) in the form of sodium salts in green oxidation routes of …

Novel polyoxometalate@ g-C3N4 hybrid photocatalysts for degradation of dyes and phenolics

J He, H Sun, S Indrawirawan, X Duan, MO Tade… - Journal of colloid and …, 2015 - Elsevier
Graphitic carbon nitride (gC 3 N 4) is an emerging metal-free catalyst, and has attracted
considerate research interests in photocatalysis. For improving the low photocatalytic activity …

Spectroscopic, Crystallographic, and Electrochemical Study of Different Manganese (II)‐Substituted Keggin‐Type Phosphomolybdates

JC Raabe, J Albert, MJ Poller - Chemistry–A European Journal, 2022 - Wiley Online Library
Adjusting the RedOx activity of polyoxometalate catalysts is a key challenge for the catalysis
of selective oxidation reactions. For this purpose, the possibility of influencing the RedOx …

Highly active deep HDS catalysts prepared using Mo and W heteropolyacids supported on SBA-15

L Lizama, T Klimova - Applied Catalysis B: Environmental, 2008 - Elsevier
A series of Mo (W) catalysts promoted by Ni and supported on pure siliceous SBA-15 was
prepared using Keggin-type heteropolyacids (H3PMo12O40 or H3PW12O40) as active …

Tetrabutyl ammonium salts of Keggin-type vanadium-substituted phosphomolybdates and phosphotungstates for selective aerobic catalytic oxidation of benzyl alcohol

J Díaz, LR Pizzio, G Pecchi, CH Campos, L Azocar… - Catalysts, 2022 - mdpi.com
A series of tetrabutyl ammonium (TBA) salts of V-included Keggin-type polyoxoanions with
W (TBA4PW11V1O40 and TBA5PW10V2O40) and Mo (TBA4PMo11V1O40 and …

Vanadium-doped phosphomolybdic acids as catalysts for geraniol oxidation with hydrogen peroxide

MJ da Silva, JAV Torres, CB Vilanculo - RSC advances, 2022 - pubs.rsc.org
In this work, vanadium-doped phosphomolybdic acids were evaluated as catalysts in green
oxidation routes of terpene alcohols with hydrogen peroxide. A series of phosphomolybdic …