Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Light in gold catalysis

S Witzel, ASK Hashmi, J Xie - Chemical Reviews, 2021 - ACS Publications
Within the wide family of gold-catalyzed reactions, gold photocatalysis intrinsically features
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …

Recent development of aryl diazonium chemistry for the derivatization of aromatic compounds

F Mo, D Qiu, L Zhang, J Wang - Chemical Reviews, 2021 - ACS Publications
Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

The merger of transition metal and photocatalysis

J Twilton, C Le, P Zhang, MH Shaw, RW Evans… - Nature Reviews …, 2017 - nature.com
The merger of transition metal catalysis and photocatalysis, termed metallaphotocatalysis,
has recently emerged as a versatile platform for the development of new, highly enabling …

The interplay of carbophilic activation and Au (I)/Au (III) catalysis: an emerging technique for 1, 2-difunctionalization of C–C multiple bonds

VW Bhoyare, AG Tathe, A Das, CC Chintawar… - Chemical Society …, 2021 - pubs.rsc.org
Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Photoredox catalysis in organic chemistry

MH Shaw, J Twilton… - The Journal of organic …, 2016 - ACS Publications
In recent years, photoredox catalysis has come to the forefront in organic chemistry as a
powerful strategy for the activation of small molecules. In a general sense, these approaches …

Dual catalysis strategies in photochemical synthesis

KL Skubi, TR Blum, TP Yoon - Chemical reviews, 2016 - ACS Publications
The interaction between an electronically excited photocatalyst and an organic molecule
can result in the genertion of a diverse array of reactive intermediates that can be …

Merging visible light photoredox and gold catalysis

MN Hopkinson, A Tlahuext-Aca… - Accounts of Chemical …, 2016 - ACS Publications
Conspectus Since the beginning of this century, π-Lewis acidic gold complexes have
become the catalysts of choice for a wide range of organic reactions, especially those …

Merging visible light photoredox catalysis with metal catalyzed C–H activations: on the role of oxygen and superoxide ions as oxidants

DC Fabry, M Rueping - Accounts of chemical research, 2016 - ACS Publications
Conspectus The development of efficient catalytic systems for direct aromatic C–H bond
functionalization is a long-desired goal of chemists, because these protocols provide …