The development of (bio) catalysts capable of selectively activating strong C–H bonds is a continuing challenge in modern chemistry. In both metalloenzymes and synthetic systems …
A series of organometallic copper complexes in formal oxidation states ranging from+ 1 to+ 3 have been characterized by a combination of Cu K-edge X-ray absorption (XAS) and Cu …
Y Wu, C Zhao, Y Su, S Shaik… - Angewandte Chemie …, 2023 - Wiley Online Library
The copper‐dependent formylglycine‐generating enzyme (FGE) catalyzes the oxygen‐ dependent oxidation of specific peptidyl‐cysteine residues to formylglycine. Our QM/MM …
I Gerz, SAV Jannuzzi, KT Hylland… - European Journal of …, 2021 - Wiley Online Library
A series of Cu (I) complexes of bidentate or tetradentate Schiff base ligands bearing either 1‐ H‐imidazole or pyridine moieties were synthesized. The complexes were studied by a …
Valence-to-core (VtC) X-ray emission spectroscopy offers the opportunity to probe the valence electronic structure of a system filtered by selection rules. From this, the nature of its …
This study investigates the influence of ligand charge on transition energies in a series of CuN2S2 complexes based on dithiocarbazate Schiff base ligands using Cu K-edge X-ray …
PN Phu, CE Gutierrez, S Kundu, D Sokaras… - Inorganic …, 2020 - ACS Publications
A series of β-diketiminate Ni–NO complexes with a range of NO binding modes and oxidation states were studied by X-ray emission spectroscopy (XES). The results …
Y Liu, J Berry-Gair, Z Wang, L Kang, B Wang, X Guan… - 2023 - chemrxiv.org
Cu-exchanged zeolite is an efficient catalyst to remove harmful nitrogen oxides from diesel exhaust gas through the selective catalytic reduction (SCR) reaction. The SCR performance …
Eliminating the harmful NOx, which is the major pollutant in the exhaust gas of diesel engines, has long been the pursue of scientists. Cu-chabazite (Cu-CHA) zeolites system …