Brønsted acidity in metal–organic frameworks

J Jiang, OM Yaghi - Chemical reviews, 2015 - ACS Publications
The past 20 years have witnessed rapid development of reticular chemistry, 1, 2 which is
concerned with linking molecular building units with strong chemical bonds to form …

Lewis acids: from conventional homogeneous to green homogeneous and heterogeneous catalysis

A Corma, H Garcia - Chemical Reviews, 2003 - ACS Publications
Acid-catalyzed reactions are by far the most numerous and best-studied reaction type, 1-5 in
which organic functional groups undergo an array of different transformations with …

Superacidity in sulfated metal–organic framework-808

J Jiang, F Gándara, YB Zhang, K Na… - Journal of the …, 2014 - ACS Publications
Superacids, defined as acids with a Hammett acidity function H 0≤− 12, are useful
materials, but a need exists for new, designable solid state systems. Here, we report …

Identification of the strong Brønsted acid site in a metal–organic framework solid acid catalyst

CA Trickett, TM Osborn Popp, J Su, C Yan… - Nature …, 2019 - nature.com
It remains difficult to understand the surface of solid acid catalysts at the molecular level,
despite their importance for industrial catalytic applications. A sulfated zirconium-based …

Sulfated zirconia and its modified versions as promising catalysts for industrial processes

GD Yadav, JJ Nair - Microporous and mesoporous materials, 1999 - Elsevier
Zirconium oxide, or zirconia, when modified with anions such as sulfate ions forms a highly
acidic or superacidic catalyst depending on the treatment conditions. This catalyst is found to …

Use of solid catalysts in Friedel− Crafts acylation reactions

G Sartori, R Maggi - Chemical reviews, 2006 - ACS Publications
“The first mention of acylation related to the later Al2Cl6 method of Friedel and Crafts
appeared in 1873 in a preliminary communication by Grucarevic and Merz....” 1 With these …

Sulfated zirconia-based strong solid-acid catalysts: recent progress

X Song, A Sayari - Catalysis Reviews, 1996 - Taylor & Francis
This review article deals with recent progress in the preparation of sulfated zirconia (SZ)-
bassed, strong solid-acid catalysts, the characterization of their physicochemical properties …

Synthesis of Ti (SO4) O solid acid nano-catalyst and its application for biodiesel production from used cooking oil

J Gardy, A Hassanpour, X Lai, MH Ahmed - Applied Catalysis A: General, 2016 - Elsevier
A novel solid acid nano-catalyst [Ti (SO 4) O] was synthesised and used for the
simultaneous esterification and transesterification of free fatty acids in used cooking oil …

[图书][B] Zeolites for cleaner technologies

M Guisnet, JP Gilson - 2002 - researchgate.net
Clean Technologies, Environmentally Friendly Processes, Clean Products and Green
Chemistry..., are terms encountered with an increased frequency by politicians as well as by …

Genesis of Brønsted acid sites during dehydration of 2-butanol on tungsten oxide catalysts

CD Baertsch, KT Komala, YH Chua, E Iglesia - Journal of Catalysis, 2002 - Elsevier
In situ measurements of Brønsted acid sites (by titration with 2, 6-di-tert-butyl-pyridine) and
reduced centers (by UV–vis spectroscopy) were carried out on WOx–ZrO2 with catalysts at …