On the welding of vitrimers: Chemistry, mechanics and applications

Q Shi, C Jin, Z Chen, L An… - Advanced Functional …, 2023 - Wiley Online Library
Linear chains in thermoplastics make them relatively weak in performance but inherently
weldable and recyclable. By contrast, thermosets with permanently crosslinked networks …

Biobased transesterification vitrimers

A Kumar, LA Connal - Macromolecular Rapid Communications, 2023 - Wiley Online Library
The rapid increase in the use of plastics and the related sustainability issues, including the
depletion of global petroleum reserves, have rightly sparked interest in the use of biobased …

Polyolefins vitrimers: design principles and applications

M Ahmadi, A Hanifpour, S Ghiassinejad… - Chemistry of …, 2022 - ACS Publications
Less than 10% of plastics are recycled worldwide, among which polyolefins, which form two-
thirds of all produced polymers, are the most discarded ones. This stems from the nonpolar …

Vanillin-based epoxy vitrimers: looking at the cystamine hardener from a different perspective

S Guggari, F Magliozzi, S Malburet… - ACS Sustainable …, 2023 - ACS Publications
Epoxy vitrimers encompass many advantages compared to traditional epoxy materials such
as recyclability, repairability, and reprocessability. These properties are induced by the …

Multiple H‐Bonding Cross‐Linked Supramolecular Solid–Solid Phase Change Materials for Thermal Energy Storage and Management

C Wang, X Geng, J Chen, H Wang, Z Wei… - Advanced …, 2024 - Wiley Online Library
Solid–solid phase change materials (SSPCMs) are considered among the most promising
candidates for thermal energy storage and management. However, the application of …

Covalent Adaptable Networks through Dynamic N,S-Acetal Chemistry: Toward Recyclable CO2-Based Thermosets

T Habets, G Seychal, M Caliari… - Journal of the …, 2023 - ACS Publications
Finding new chemistry platforms for easily recyclable polymers has become a key challenge
to face environmental concerns and the growing plastics demand. Here, we report a …

Thermally latent bases in dynamic covalent polymer networks and their emerging applications

D Reisinger, MU Kriehuber, M Bender… - Advanced …, 2023 - Wiley Online Library
A novel strategy allowing temporal control of dynamic bond exchange in covalently
crosslinked polymer networks via latent transesterification catalysts is introduced. Obtained …

From biomass to vitrimers: Latest developments in the research of lignocellulose, vegetable oil, and naturally-occurring carboxylic acids

Y Yang, H Liu, B Lin, D Tang, J Xu, L Dai… - Industrial Crops and …, 2023 - Elsevier
Thermosets are widely used for their excellent properties, but their permanent cross-linking
makes them difficult to recycle. Covalent adaptive networks can address the recycling of …

Exploring the Limits of High-Tg Epoxy Vitrimers Produced through Resin-Transfer Molding

V Schenk, R D'elia, P Olivier, K Labastie… - … Applied Materials & …, 2023 - ACS Publications
Over the past few years, scientists have developed new ways to overcome the recycling
issues of conventional thermosets with the introduction of associative covalent adaptable …

Solvent-free preparation of imine vitrimers: leveraging benzoxazine crosslinking for melt processability and tunable mechanical performance

LJ Hamernik, W Guzman, JS Wiggins - Journal of Materials Chemistry …, 2023 - pubs.rsc.org
Covalent adaptable networks, particularly imine vitrimers, have received considerable
attention for the design of recyclable and reprocessable thermoset-like materials. However …