Recent advances and applications of p-toluenesulfonylmethyl isocyanide (TosMIC)
AD Mathiyazhagan, G Anilkumar - Organic & Biomolecular Chemistry, 2019 - pubs.rsc.org
Since its introduction in 1972, TosMIC (p-toluenesulfonylmethyl isocyanide) has been
recognised as an important building block in organic synthesis and a wide range of reaction …
recognised as an important building block in organic synthesis and a wide range of reaction …
Calix [3] arene-analogous metacyclophanes: Synthesis, structures and properties with infinite potential
Calixarene-analogous metacyclophanes (CAMs) are a special class of cyclophanes that are
cyclic polyaromatic hydrocarbons containing three or more aromatic rings linked by one or …
cyclic polyaromatic hydrocarbons containing three or more aromatic rings linked by one or …
Conformational Effects of Regioisomeric Substitution on the Catalytic Activity of Copper/Calix [8] arene C− S Coupling
A Berlanga‐Vázquez, RA Talmazan… - European Journal of …, 2023 - Wiley Online Library
Functionalization of the phenolic rim of p‐tert‐butylcalix [8] arene with phenanthroline to
create a cavity leads to formation of two regioisomers. Substitution of positions 1 and 5 …
create a cavity leads to formation of two regioisomers. Substitution of positions 1 and 5 …
Chlorotrimethylsilane and Sodium Iodide: A Useful Combination for the Regioselective Deoxygenation of Arylalkyl‐α‐Diketones
An efficient regioselective deoxygenation of arylalkyl‐1, 2‐diketones by the couple
trimethylsilylchloride/sodium iodide has been reported. In all cases, the deoxygenation takes …
trimethylsilylchloride/sodium iodide has been reported. In all cases, the deoxygenation takes …
Synthesis, structural properties, electrophilic substitution reactions and DFT computational studies of calix [3] benzofurans
Calix [3] benzofurans have been synthesized by a modified TosMIC coupling reaction,
followed by acid treatment and an intramolecular cyclization reaction with TMSI …
followed by acid treatment and an intramolecular cyclization reaction with TMSI …
Synthesis, Conformational Properties and DFT Computational Studies of [3] Metacyclo [3](1, 3) pyrenophanes
Abstract Two new 6, 17‐di‐tert‐butyl‐[3] metacyclo [3](1, 3)‐pyrenophane‐2, 11‐diones 8 a–
b were synthesized by the coupling reaction of 1, 3‐bis (bromomethyl)‐7‐tert‐butylpyrene 5 …
b were synthesized by the coupling reaction of 1, 3‐bis (bromomethyl)‐7‐tert‐butylpyrene 5 …
Efforts toward the Total Synthesis of Elisabethin A
M Kaiser, D Schönbauer, K Schragl… - The Journal of …, 2022 - ACS Publications
We describe our efforts toward the total synthesis of the natural product elisabethin A. The
first route was guided by the proposed biosynthesis, assembling the 6, 6-ring system before …
first route was guided by the proposed biosynthesis, assembling the 6, 6-ring system before …
Demethylation of 5, n-di-tert-butyl-8, n-dimethoxy [2. n] metacyclophane-1-ynes with BBr3 to afford novel [n] benzofuranophanes
Abstract Novel [n] benzofuranophanes (n= 8 & 10) 2a–b have been prepared by successive
intramolecular cyclization from 5, 19-di-tert-butyl-8, 22-dimethoxy [n] metacyclophane-1-yne …
intramolecular cyclization from 5, 19-di-tert-butyl-8, 22-dimethoxy [n] metacyclophane-1-yne …
Synthesis, Conformational Properties and DFT Computational Studies of Polymethyl‐Substituted [3.3] Metacyclophanes
Abstract Polymethyl substituted [3.3] metacyclophanes (MCPs) 4 a–d, were synthesized by
the TosMIC coupling method followed by Wolff–Kishner reduction of the corresponding …
the TosMIC coupling method followed by Wolff–Kishner reduction of the corresponding …
Synthesis and DFT conformational analysis of trimethyl-functionalized [2.2] metacyclophanes and their Lewis-acid assisted reactions
The synthesis of the strained trimethyled anti-[2.2] metacyclophanes 5a and 5b is reported.
They were synthesized by ring contraction of the corresponding unstrained cyclic precursors …
They were synthesized by ring contraction of the corresponding unstrained cyclic precursors …