[HTML][HTML] Pure shift NMR

K Zangger - Progress in nuclear magnetic resonance spectroscopy, 2015 - Elsevier
Although scalar-coupling provides important structural information, the resulting signal
splittings significantly reduce the resolution of NMR spectra. Limited resolution is a particular …

“Perfecting” pure shift HSQC: full homodecoupling for accurate and precise determination of heteronuclear couplings

L Kaltschnee, A Kolmer, I Timári, V Schmidts… - Chemical …, 2014 - pubs.rsc.org
Fully homodecoupled HSQC spectra can be obtained through the use of a new pulse
sequence element,“perfectBIRD”. By way of illustration, we show that perfectBIRD …

Nuclear spin singlet order selection by adiabatically ramped RF fields

AS Kiryutin, AN Pravdivtsev… - The Journal of …, 2016 - ACS Publications
We describe an NMR method to generate singlet order in spin pairs from longitudinal spin
magnetization and suppress residual background signals. This method can also be used for …

19F NMR-Guided Design of Glycomimetic Langerin Ligands

EC Wamhoff, J Hanske, L Schnirch, J Aretz… - ACS Chemical …, 2016 - ACS Publications
C-type lectin receptors (CLRs) play a pivotal role in pathogen defense and immune
homeostasis. Langerin, a CLR predominantly expressed on Langerhans cells, represents a …

New experimental evidence for pervasive dynamics in proteins

ERP Zuiderweg, DA Case - Protein Science, 2023 - Wiley Online Library
There is ample computational, but only sparse experimental data suggesting that pico‐ns
motions with 1 Å amplitude are pervasive in proteins in solution. Such motions, if present in …

Broadband measurement of true transverse relaxation rates in systems with coupled protons: application to the study of conformational exchange

P Kiraly, G Dal Poggetto, L Castanar, M Nilsson… - Chemical …, 2021 - pubs.rsc.org
Accurate measurement of transverse relaxation rates in coupled spin systems is important in
the study of molecular dynamics, but is severely complicated by the signal modulations …

Measurement of T1/T2 relaxation times in overlapped regions from homodecoupled 1H singlet signals

L Castañar, P Nolis, A Virgili, T Parella - Journal of Magnetic Resonance, 2014 - Elsevier
The implementation of the HOmodecoupled Band-Selective (HOBS) technique in the
conventional Inversion-Recovery and CPMG-based PROJECT experiments is described …

A pure shift experiment with increased sensitivity and superior performance for strongly coupled systems

J Ilgen, L Kaltschnee, CM Thiele - Journal of Magnetic Resonance, 2018 - Elsevier
Motivated by the persisting need for enhanced resolution in solution state NMR spectra,
pure shift techniques such as Zangger-Sterk decoupling have recently attracted widespread …

New pulse sequence for robust filtering of hyperpolarized multiplet spin order

AN Pravdivtsev, KL Ivanov, AV Yurkovskaya… - Doklady Physical …, 2015 - Springer
Abstract A new Nuclear Magnetic Resonance (NMR) pulse sequence is proposed for
manipulating ParaHydrogen Induced Polarization (PHIP) at high magnetic fields. The …

Elimination of Zero-Quantum artifacts and sensitivity enhancement in perfect echo based 2D NOESY

B Baishya, A Verma - Journal of Magnetic Resonance, 2015 - Elsevier
Zero-Quantum artifacts seriously degrade the performance of 2D NOESY. Homonuclear J-
evolution during t 1 period generates Zero-Quantum and other higher quantum coherences …