Synthesis and characterization of mixed valence cobalt (III)/cobalt (II) complexes with N, O-donor Schiff base ligands

A Banerjee, S Chattopadhyay - Polyhedron, 2019 - Elsevier
The review is focused to discuss the synthetic strategy and properties of mixed valence
cobalt (III)/cobalt (II) complexes with N, O-donor Schiff base ligands. Use of compartmental …

Heterometallic 3d–4f single molecule magnets containing diamagnetic metal ions

A Chakraborty, J Goura, P Kalita, A Swain… - Dalton …, 2018 - pubs.rsc.org
Molecular nano magnets such as single-molecule magnets (SMMs) are a class of
coordination complexes with numerous potential applications such as information storage …

α-Amino acids: Natural and artificial building blocks for discrete polymetallic clusters

AB Canaj, FΕ Kakaroni, A Collet, CJ Milios - Polyhedron, 2018 - Elsevier
In this report we attempt to describe and review the employment of α-amino acid ligands for
the construction of metallic complexes. We focus our interest on the synthesis of discrete …

A difunctional azido-cobalt (II) coordination polymer exhibiting slow magnetic relaxation behaviour and high-energy characteristics with good thermostability and …

X Ma, Y Liu, W Song, Z Wang, X Liu, G Xie… - Dalton …, 2018 - pubs.rsc.org
A novel one-dimensional azido-cobalt (II) compound,[Co2 (1-mbt) 2 (N3) 4] n (1)(1-mbt= 1-
((2-propyl-imidazol-1-yl) methyl)-benzo [1, 2, 3] triazole), was solvothermally synthesized. X …

A tetracobalt (ii) cluster with a two vertex truncated dicubane topology endogenously supported by carboxylate-based (2-pyridyl) methylamine ligands: magneto …

S Kant, S Saha, F Lloret, J Cano, R Mukherjee - Dalton Transactions, 2023 - pubs.rsc.org
A reaction between CoCl2 and L3-(CO2−) 2 (2: 1 stoichiometry) in CH3OH affords a discrete
complex [CoII4-{L3-(CO2−) 2} 2 (μ3-OCH3) 2 (CH3OH) 2 (H2O) 2Cl2](1)[L3-(CO2−) 2= 3-[N …

Synthesis, Structure, and Magnetic Properties of Two {Co16IICo4III} Supertetrahedral T4 Clusters Formed from the In Situ Dissociation of a Tertiary N-Containing …

MY Xu, TW Zhang, ZM Xian, J Yang… - Crystal Growth & …, 2023 - ACS Publications
Two mixed-valent cobalt clusters {[(CoII) 16 (CoIII) 4 (μ6-O) 4 (μ3-OH) 12 (OCH3) 12 (H2O) 8
(BMBC) 4]·(NO3) 8}(1) and {[(CoII) 16 (CoIII) 4 (μ3-OH) 20 (OCH2CH3) 4 (HOCH2CH3) 8 …

Synthesis, magnetism and spectral studies of six defective dicubane tetranuclear {M 4 O 6}(M= Ni II, Co II, Zn II) and three trinuclear Cd II complexes with polydentate …

L Jiang, DY Zhang, JJ Suo, W Gu, JL Tian, X Liu… - Dalton …, 2016 - pubs.rsc.org
A series of NiII, CoII, ZnII and CdII complexes 1–9 with polytopic Schiff base ligands have
been synthesized. The single-crystal X-ray crystallography results show that tetranuclear …

Metal–metalloligand coordination polymer embedding triangular cobalt–oxo clusters: solvent-and temperature-induced crystal to crystal transformations and …

K Fan, F Xu, M Kurmoo, XD Huang, CH Liao… - Inorganic …, 2020 - ACS Publications
Reaction of the metalloligand IrIII (ppy-COOH) 3 and the anisotropic paramagnetic CoII ion
under solvothermal conditions resulted in a metal–metalloligand coordination …

Synthesis, structural characterization and magnetic behaviour of a family of [Co III2 Ln III2] butterfly compounds

AV Funes, L Carrella, Y Rechkemmer… - Dalton …, 2017 - pubs.rsc.org
We have successfully prepared and structurally characterized a family of butterfly-like
[CoIII2LnIII2] complexes where all magnetic properties are due to the Ln (III) ions. The …

Anisotropic exchange interaction and field-induced SMM behaviour in a mixed valence {Co II4 Co III2} complex

D Cabrosi, C Cruz, V Paredes-García, P Alborés - Dalton Transactions, 2021 - pubs.rsc.org
We are reporting the synthesis and structural characterization of a new hexanuclear Co
(II)/Co (III) complex starting from a versatile pivalate cobalt precursor and the racemic …