Emerging trends in polymerization-induced self-assembly

NJW Penfold, J Yeow, C Boyer, SP Armes - ACS Macro Letters, 2019 - ACS Publications
In this Perspective, we summarize recent progress in polymerization-induced self-assembly
(PISA) for the rational synthesis of block copolymer nanoparticles with various …

RAFT‐mediated polymerization‐induced self‐assembly

F d'Agosto, J Rieger, M Lansalot - … Chemie International Edition, 2020 - Wiley Online Library
After a brief history that positions polymerization‐induced self‐assembly (PISA) in the field of
polymer chemistry, this Review will cover the fundamentals of the PISA mechanism …

Organocobalt complexes as sources of carbon-centered radicals for organic and polymer chemistries

J Demarteau, A Debuigne, C Detrembleur - Chemical reviews, 2019 - ACS Publications
Organocobalt (III) complexes (R-CoIII), defined as cobalt complexes featuring a carbon–
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …

Polymerizations by RAFT: Developments of the Technique and Its Application in the Synthesis of Tailored (Co) polymers

M Semsarilar, V Abetz - Macromolecular Chemistry and Physics, 2021 - Wiley Online Library
Reversible addition–fragmentation chain transfer (RAFT) polymerization is an increasingly
popular method of controlled radical polymerization and remarkable advances is made in …

Polymerisation-induced self-assembly (PISA) as a straightforward formulation strategy for stimuli-responsive drug delivery systems and biomaterials: Recent advances

H Phan, V Taresco, J Penelle, B Couturaud - Biomaterials Science, 2021 - pubs.rsc.org
Stimuli-responsive amphiphilic block copolymers have emerged as promising nanocarriers
for enhancing site-specific and on-demand drug release in response to a range of stimuli …

Controlled radical polymerization in dispersed systems for biological applications

P Gurnani, S Perrier - Progress in Polymer Science, 2020 - Elsevier
Polymeric nanoparticles show great promise in a range of biomedical applications,
improving pharmacokinetic properties, dose requirements and immune response in drug …

RAFT polymerization-induced self-assembly as a strategy for versatile synthesis of semifluorinated liquid-crystalline block copolymer nanoobjects

L Shen, H Guo, J Zheng, X Wang, Y Yang… - ACS Macro …, 2018 - ACS Publications
Polymerization-induced self-assembly is demonstrated as a powerful platform for the
synthesis of block copolymers comprising a semifluorinated liquid-crystalline block. This …

Synthesis of Janus and patchy particles using nanogels as stabilizers in emulsion polymerization

A Lotierzo, BW Longbottom, WH Lee, SAF Bon - ACS nano, 2018 - ACS Publications
Polymer nanogels are used as colloidal stabilizers in emulsion polymerization. The
nanogels were made by the covalent cross-linking of block copolymer micelles, the …

Synthesis of transition-metal-free and sulfur-free nanoparticles and nanocapsules via reversible complexation mediated polymerization (RCMP) and polymerization …

J Sarkar, L Xiao, AW Jackson, AM Van Herk… - Polymer Chemistry, 2018 - pubs.rsc.org
NaI-catalyzed reversible complexation mediated living radical polymerization (RCMP) was
combined with polymerization induced self-assembly (PISA) to generate self-assemblies …

Polymerization‐Induced Self‐Assembly under Compressed CO2: Control of Morphology Using a CO2‐Responsive MacroRAFT Agent

D Zhou, RP Kuchel, S Dong, FP Lucien… - Macromolecular …, 2019 - Wiley Online Library
Polymerization‐induced self‐assembly of 2‐hydroxypropyl methacrylate is conducted in
water and water/MeOH using a CO2‐responsive macroRAFT agent in the form of a statistical …