Iron carbonyl compounds with aromatic dithiolate bridges as organometallic mimics of [FeFe] hydrogenases
S Gao, Y Liu, Y Shao, D Jiang, Q Duan - Coordination Chemistry Reviews, 2020 - Elsevier
Recently, substantial efforts had been made in the field of synthetic iron compounds as
structural and functional models of the hydrogenase enzyme active site for the purpose of …
structural and functional models of the hydrogenase enzyme active site for the purpose of …
Utilization of non-innocent redox ligands in [FeFe] hydrogenase modeling for hydrogen production
YC Liu, TH Yen, KT Chu, MH Chiang - Comments on Inorganic …, 2016 - Taylor & Francis
Biomimetic diiron complexes bearing redox non-innocent ligands are discussed in this
review. The complexes are synthesized to model the active site of [FeFe] hydrogenase in …
review. The complexes are synthesized to model the active site of [FeFe] hydrogenase in …
[FeFe]-Hydrogenase H-Cluster Mimics with Various −S(CH2)nS– Linker Lengths (n = 2–8): A Systematic Study
H Abul-Futouh, LR Almazahreh, MK Harb… - Inorganic …, 2017 - ACS Publications
The effect of the nature of the dithiolato ligand on the physical and electrochemical
properties of synthetic H-cluster mimics of the [FeFe]-hydrogenase is still of significant …
properties of synthetic H-cluster mimics of the [FeFe]-hydrogenase is still of significant …
Toward a tunable synthetic [FeFe]-hydrogenase H-cluster mimic mediated by perylene monoimide model complexes: Insight into molecular structures and …
H Abul-Futouh, A Skabeev, D Botteri… - …, 2018 - ACS Publications
The nature of the bridging dithiolate has an important role on tuning the physical and
electrochemical properties of the synthetic H-cluster mimics of [FeFe]-hydrogenase and still …
electrochemical properties of the synthetic H-cluster mimics of [FeFe]-hydrogenase and still …
Novel Ruthenium Phthalocyanine-Containing Model Complex for the Active Site of [FeFe]-Hydrogenases: Synthesis, Structural Characterization, and Catalytic H2 …
LC Song, FX Luo, BB Liu, ZC Gu, H Tan - Organometallics, 2016 - ACS Publications
The first phthalocyanine (Pc) macrocycle-containing [FeFe]-hydrogenase model complex,(i-
BuO) 8PcRu (CO)(μ-PDT)[(Ph2P) 2NCH2C5H4N] Fe2 (CO) 4 (6), has been prepared by a …
BuO) 8PcRu (CO)(μ-PDT)[(Ph2P) 2NCH2C5H4N] Fe2 (CO) 4 (6), has been prepared by a …
Synthesis and electrochemical investigations of the ortho-metalated complexes [Fe2 (CO) 6 {к, μ-S, η2-(R)}] and their substitution reactions
AQ Daraosheh, H Abul-Futouh, H Görls… - Inorganica Chimica …, 2020 - Elsevier
Modifications of the dithiolate linkers that connect the two iron atoms of the synthetic H-
cluster mimics of [FeFe]-hydrogenase play a significant role on tuning its physical and …
cluster mimics of [FeFe]-hydrogenase play a significant role on tuning its physical and …
Synthesis and Electrochemical Investigations of the [FeFe]‐Hydrogenase H‐Cluster Mimics Mediated by Bicyclic Dithiols Derivative
AQ Daraosheh, H Abul‐Futouh… - Zeitschrift für …, 2021 - Wiley Online Library
Biomimic of the active site of [FeFe]‐hydrogenase containing bicyclic dithiols as bridging
linker has been synthesized and characterized using different spectroscopic methods. The …
linker has been synthesized and characterized using different spectroscopic methods. The …
Electrochemical and Computational Insights into the Reduction of [Fe2(CO)6{µ-(SCH2)2GeMe2}] Hydrogenase H-Cluster Mimic
The electrochemical reduction of the complex [Fe2 (CO) 6 {µ-(SCH2) 2GeMe2}](1) under N2
and CO is reported applying cyclic voltammetry. Reduction of complex 1 in CO saturated …
and CO is reported applying cyclic voltammetry. Reduction of complex 1 in CO saturated …
Síntesis de sistemas polimetálicos biofuncionales
A Durán Merinero - 2019 - docta.ucm.es
En la actualidad, la principal fuente de energía tanto en el sector industrial como en el
sector del trasporte sigue proviniendo principalmente de los combustibles fósiles, como el …
sector del trasporte sigue proviniendo principalmente de los combustibles fósiles, como el …
Varying the flexibility of the aromatic backbone in half sandwich rhodium (III) dithiolato complexes: A synthetic, spectroscopic and structural investigation
A series of rhodium (III) half sandwich complexes of the type [Cp* Rh (PMe3)(S–R–S)]; S–R–
S= naphthalene-1, 8-dithiolate, acenaphthene-5, 6-dithiolate,[1, 1'-biphenyl]-2, 2'-dithiolate …
S= naphthalene-1, 8-dithiolate, acenaphthene-5, 6-dithiolate,[1, 1'-biphenyl]-2, 2'-dithiolate …