Late-metal catalysts for ethylene homo-and copolymerization

SD Ittel, LK Johnson, M Brookhart - Chemical Reviews, 2000 - ACS Publications
Polyolefins are a multibillion dollar a year industry with worldwide production in excess of
160 billion pounds and polyethylene alone in excess of 100 billion pounds. Despite this size …

Catalytic activities of Schiff base transition metal complexes

KC Gupta, AK Sutar - Coordination Chemistry Reviews, 2008 - Elsevier
Many Schiff base complexes of metal ions show high catalytic activity. Chiral Schiff base
complexes are more selective in various reactions such as oxidation, hydroxylation, aldol …

Advances in non-metallocene olefin polymerization catalysis

VC Gibson, SK Spitzmesser - Chemical reviews, 2003 - ACS Publications
The field of olefin polymerization catalysis has experienced a phenomenal acceleration in
research activity over the past 5 years, with many academic and industrial research …

Cocatalysts for metal-catalyzed olefin polymerization: activators, activation processes, and structure− activity relationships

EYX Chen, TJ Marks - Chemical Reviews, 2000 - ACS Publications
One of the most exciting developments in the areas of catalysis, organometallic chemistry,
and polymer science in recent years has been the intense exploration and …

Toward the copolymerization of propylene with polar comonomers

SLJ Luckham, K Nozaki - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus Polyolefins are produced in vast amounts and are found in so many consumer
products that the two most commonly produced forms, polyethylene (PE) and polypropylene …

Polymerization of lactide with zinc and magnesium β-diiminate complexes: stereocontrol and mechanism

BM Chamberlain, M Cheng, DR Moore… - Journal of the …, 2001 - ACS Publications
A series of zinc (II) and magnesium (II) alkoxides based upon a β-diiminate ligand
framework has been prepared.[(BDI-1) ZnO i Pr] 2 [(BDI-1)= 2-((2, 6-diisopropylphenyl) …

Electronic structure and catalysis on metal surfaces

J Greeley, JK Nørskov… - Annual review of physical …, 2002 - annualreviews.org
▪ Abstract The powerful computational resources available to scientists today, together with
recent improvements in electronic structure calculation algorithms, are providing important …

Precise control of polyolefin stereochemistry using single-site metal catalysts

GW Coates - Chemical Reviews, 2000 - ACS Publications
Staudinger predicted a correlation between the physical properties of a polymer and its main-
chain stereochemistry as early as 1929. 1 However it was not until 1947 that Schildknecht …

Iron and cobalt ethylene polymerization catalysts bearing 2, 6-bis (imino) pyridyl ligands: synthesis, structures, and polymerization studies

GJP Britovsek, M Bruce, VC Gibson… - Journal of the …, 1999 - ACS Publications
The synthesis, characterization, and ethylene polymerization behavior of a series of iron and
cobalt halide complexes, LMX n (M= Fe, X= Cl, n= 2, 3, X= Br, n= 2; M= Co, X= Cl, n= 2) …

Bis (imino) pyridines: Surprisingly reactive ligands and a gateway to new families of catalysts

VC Gibson, C Redshaw, GA Solan - Chemical reviews, 2007 - ACS Publications
It has been almost a decade since sterically demanding bis (arylimino) pyridine ligands,[2, 6-
(ArNdCR) 2C5H3N](1)(Figure 1), were found to impart late transition metals, especially iron …