Understanding the energy it takes to build or break chemical bonds is essential for scientists and engineers in a wide range of innovative fields, including catalysis, nanomaterials …
The comparative catalytic activities of iron phosphides, Fe x P (x= 1–3), have been established with phase-pure material grown by chemical vapor deposition (CVD) from single …
LA van der Veen, MDK Boele… - Journal of the …, 1998 - ACS Publications
The electronic effect in the rhodium diphosphine catalyzed hydroformylation was investigated. A series of electronically modified thixantphos ligands was synthesized, and …
N Fey, AG Orpen, JN Harvey - Coordination Chemistry Reviews, 2009 - Elsevier
Changing the coordinated ligands is a powerful and synthetically convenient way of modifying and fine-tuning the properties of transition metal complexes, especially those …
Abstract The hydroformylation (or “oxo”) reaction is one of the important reactions for the manufacture of building blocks for the chemical industry. This reaction is among the most …
A Roodt, S Otto, G Steyl - Coordination Chemistry Reviews, 2003 - Elsevier
This paper deals with the synthesis of rhodium (I) Vaska-type complexes of the general form trans-[Rh (CO) X (PX3)](X= halide, X aryl or alkyl substituent) when incorporating tertiary …
SH Chikkali, JI van der Vlugt, JNH Reek - Coordination chemistry reviews, 2014 - Elsevier
This review aims to illustrate recent advances in the application of hybrid diphosphorus ligands for the Rh catalysed hydroformylation of alkenes, discussing the most prevalent …
N Sieffert, M Bühl - Inorganic chemistry, 2009 - ACS Publications
The binding enthalpy of a triphenylphosphine ligand in Ru (CO) Cl (PPh3) 3 (CH CHPh) is studied with “standard”(BP86 and B3LYP), dispersion-corrected (B3LYP-D and B97-D), and …