Natural and Synthetic Chromenes, Fused Chromenes, and Versatility of Dihydrobenzo[h]chromenes in Organic Synthesis

R Pratap, VJ Ram - Chemical reviews, 2014 - ACS Publications
1. INTRODUCTION Bicyclic oxygen heterocycles resulting from fusion of benzene ring with
5, 6-positions of either 2H-or 4H-pyran ring system are designated as 2H-chromene (2H-1 …

Metal complex catalysis in the synthesis of spirocarbocycles

VA D'yakonov, OA Trapeznikova, A de Meijere… - Chemical …, 2014 - ACS Publications
Spirans contain at least two rings, which share one carbon atom called the spirocarbon
atom. 1 Synthetic and natural spirocarbocycles attract the attention of organic chemists due …

RuII-Catalyzed Vinylative Dearomatization of Naphthols via a C(sp2)–H Bond Activation Approach

J Nan, Z Zuo, L Luo, L Bai, H Zheng… - Journal of the …, 2013 - ACS Publications
Intermolecular annulation reactions of 1-aryl-2-naphthols with internal alkynes proceed
efficiently in the presence of a Ru catalyst and a Cu oxidant to generate spirocyclic …

Grubbs' ruthenium-carbenes beyond the metathesis reaction: less conventional non-metathetic utility

B Alcaide, P Almendros, A Luna - Chemical reviews, 2009 - ACS Publications
Metal-catalyzed olefin metathesis has become one of the most widely used organometallic
transformations for carbon-carbon formation in organic synthesis. For this reason, the Royal …

2‐Iodoxybenzoic acid—a simple oxidant with a dazzling array of potential applications

A Duschek, SF Kirsch - Angewandte Chemie International …, 2011 - Wiley Online Library
Since its discovery by Christoph Hartmann and Victor Meyer in 1893, 2‐iodoxybenzoic acid
(IBX) has emerged as a rather ubiquitous oxidant for organic synthesis. The past decade …

Cycloadditions and cyclizations of acetylenic, allenic, and conjugated dienyl sulfones

TG Back, KN Clary, D Gao - Chemical reviews, 2010 - ACS Publications
Sulfones display a diverse range of behavior and possess unique features that make them
valuable for numerous types of synthetic applications. As a result of their utility and …

Selected synthetic strategies to spirocyclics

S Kotha, AC Deb, K Lahiri, E Manivannan - Synthesis, 2009 - thieme-connect.com
The design and synthesis of spirocycles is a challenging task because it involves the
creation of a quaternary center, which itself is considered to be one of the most difficult tasks …

Photosensitization enables Pauson-Khand–type reactions with nitrenes

F Li, WF Zhu, C Empel, O Datsenko, A Kumar, Y Xu… - Science, 2024 - science.org
The Pauson-Khand reaction has in the past 50 years become one of the most common
cycloaddition reactions in chemistry. Coupling two unsaturated bonds with carbon …

Design and synthesis of spirocycles

S Kotha, NR Panguluri, R Ali - European Journal of Organic …, 2017 - Wiley Online Library
In this account we disclose a variety of simple strategies demonstrated in our laboratory in
the last two decades for the assembly of diverse and intricate molecular frameworks …

Mizoroki–Heck cyclizations of amide derivatives for the introduction of quaternary centers

JM Medina, J Moreno, S Racine, S Du… - Angewandte …, 2017 - Wiley Online Library
We report non‐decarbonylative Mizoroki–Heck reactions of amide derivatives. The
transformation relies on the use of nickel catalysis and proceeds using sterically hindered tri …