Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …

Crystal engineering of coordination polymers with structure-based properties is of great
current interest.(1) Coordination polymers are a new kind of molecular materials which have …

Electrochemical reduction of CO2 to obtain high-value-added feedstocks is a promising
strategy to alleviate the energy crisis. Cu-based catalysts generate multi-carbon products …

Chemical systems consist of chemical elements and chemical bonds. Strong, covalent
bonds are expected between open-shell species, when more bonding molecular orbitals …

In the past two decades, the vast classes of coordination polymers (CPs) and metal–organic
frameworks (MOFs) have received deep attention in both the academic and industrial …

In 1967 Pederson reported the synthesis of macrocyclic crown ethers and their ability to
selectively bind alkali and alkaline earth ions, 1, 2 and since then supramolecular …

Many crystalline solids cannot be prepared in the form of single crystals of sufficient size
and/or quality for investigation using single‐crystal X‐ray diffraction techniques, and the …

One-pot solvothermal treatments of organonitriles, ammonia, and CuII salts yielded CuI and
3, 5-disubstituted 1, 2, 4-triazolates. The organic triazolate components were derived from …

Synthetic details, solid-state structures, and photophysical properties of a group of trimeric
copper (I) complexes containing pyrazolate ligands are described. The reaction of copper (I) …

The synthesis and application of carbon-supported, nitrogen-based organometallic silver
catalysts for the reduction of CO2 is studied using an electrochemical flow reactor. Their …