The mechanism of the modified Ullmann reaction

E Sperotto, GPM van Klink, G van Koten… - Dalton …, 2010 - pubs.rsc.org
The copper-mediated aromatic nucleophilic substitution reactions developed by Fritz
Ullmann and Irma Goldberg required stoichiometric amounts of copper and very high …

Transition Metal‐Catalysed, Direct and Site‐Selective N1‐, C2‐or C3‐Arylation of the Indole Nucleus: 20 Years of Improvements

L Joucla, L Djakovitch - Advanced Synthesis & Catalysis, 2009 - Wiley Online Library
The direct and site‐selective transition metal‐catalysed N1‐, C2‐or C3‐arylations of indoles
have been the subject of almost continuous improvements since their discovery in early …

Catalytic C C, C N, and C O Ullmann‐Type Coupling Reactions

F Monnier, M Taillefer - Angewandte Chemie International …, 2009 - Wiley Online Library
Copper‐catalyzed Ullmann condensations are key reactions for the formation of carbon–
heteroatom and carbon–carbon bonds in organic synthesis. These reactions can lead to …

The complementary competitors: palladium and copper in C–N cross-coupling reactions

IP Beletskaya, AV Cheprakov - Organometallics, 2012 - ACS Publications
The C–N cross-coupling chemistry intensely developed since the late 1990s has supplied
synthesists with an overwhelming number of methods to effectively combine carbon and …

Katalytische C‐C‐, C‐N‐und C‐O‐Ullmann‐Kupplungen

F Monnier, M Taillefer - Angewandte Chemie, 2009 - Wiley Online Library
Abstract Kupferkatalysierte Ullmann‐Kondensationen sind Schlüsselreaktionen in der
organischen Synthese zur Bildung von Kohlenstoff‐Heteroatom‐und Kohlenstoff …

A Copper‐Catalyzed Tandem Synthesis of Indolo‐ and Pyrrolo[2,1‐a]isoquinolines

AK Verma, T Kesharwani, J Singh… - Angewandte …, 2009 - Wiley Online Library
Transition-metal-catalyzed tandem reactions have emerged as a useful tool for the synthesis
of multiring heterocyclic compounds because of the intriguing selectivity, atom economy,[1] …

Per-6-amino-β-cyclodextrin as an Efficient Supramolecular Ligand and Host for Cu(I)-Catalyzed N-Arylation of Imidazole with Aryl Bromides

P Suresh, K Pitchumani - The Journal of organic chemistry, 2008 - ACS Publications
Per-6-amino-β-cyclodextrin (per-6-ABCD), acting simultaneously as a supramolecular
ligand for CuI and host for aryl bromides, catalyzes N-arylation of imidazole with aryl …

Copper-Catalyzed Tandem Synthesis of Indolo-, Pyrrolo[2,1-a]isoquinolines, Naphthyridines and Bisindolo/Pyrrolo[2,1-a]isoquinolines via Hydroamination of ortho …

AK Verma, RR Jha, R Chaudhary… - The Journal of …, 2012 - ACS Publications
An efficient approach for the copper-catalyzed regioselective tandem synthesis of diversely
substituted indolo [2, 1-a] isoquinolines 11a–r, pyrrolo [2, 1-a] isoquinolines 12a–d, and …

MCM-41-immobilized bidentate nitrogen copper (I) complex: A highly efficient and recyclable catalyst for Buchwald N-arylation of indoles

R Xiao, H Zhao, M Cai - Tetrahedron, 2013 - Elsevier
The heterogeneous N-arylation reaction of indoles with aryl halides was achieved in toluene
at 110° C by using 4 mol% MCM-41-immobilized bidentate nitrogen copper (I) complex …

Framework‐Copper‐Catalyzed C− N Cross‐Coupling of Arylboronic Acids with Imidazole: Convenient and Ligand‐Free Synthesis of N‐Arylimidazoles

N Devarajan, P Suresh - ChemCatChem, 2016 - Wiley Online Library
A convenient and environmentally benign synthesis of N‐arylimidazoles has been
demonstrated by a straightforward reaction catalyzed by the unsaturated coordination sites …