2‐Halo Glycals as “Synthon” for 2‐C‐Branched Sugar: Recent Advances and Applications in Organic Synthesis

N Hussain, A Ahmed… - Asian Journal of Organic …, 2020 - Wiley Online Library
Glycals are unsaturated sugars having an enolic double bond present inside the ring and
act as a versatile synthon for the synthesis of natural products and biologically important …

Stereoselective assembly of C-oligosaccharides via modular difunctionalization of glycals

YN Ding, MZ Xu, YC Huang, L Ackermann… - Nature …, 2024 - nature.com
C-oligosaccharides are found in natural products and drug molecules. Despite the
considerable progress made during the last decades, modular and stereoselective synthesis …

Antioxidant and anti-sickling activity of glucal-based triazoles compounds–An in vitro and in silico study

RV Veloso, A Shamim, Y Lamarrey, HA Stefani… - Bioorganic …, 2021 - Elsevier
The sickle cell disease (SCD) has a genetic cause, characterized by a replacement of
glutamic acid to valine in the β-chain of hemoglobin. The disease has no effective treatment …

Palladium-Catalyzed Cross-Coupling of 2-Iodoglycals with N-Tosylhydrazones: Access to 2-C-Branched Glycoconjugates and Oxadecalins

J Liu, P Han, JX Liao, YH Tu, H Zhou… - The Journal of Organic …, 2019 - ACS Publications
A convenient and straightforward synthesis of diverse 2-C-alkenyl-glycosides through a
palladium-catalyzed cross-coupling reaction between 2-iodoglycals and N-tosylhydrazones …

Synthesis of amidoglucals and glucal esters via carbonylative coupling reactions of 2-iodoglucal using Mo (CO) 6 as a CO source

MP Darbem, KS Kanno, IM de Oliveira… - New Journal of …, 2019 - pubs.rsc.org
The synthesis of amidoglucals and glucal esters in good to high yields using 2-iodo-3, 4, 6-
tri-O-acetyl-D-glucal as a substrate, Mo (CO) 6 as a carbon monoxide source and PdCl2 as …

Mild Palladium‐Catalyzed Cyanation of Unprotected 2‐Iodoglycals in Aqueous Media as Versatile Tool to Access Diverse C2‐Glycoanalogues

M Malinowski, T Van Tran… - Advanced Synthesis …, 2020 - Wiley Online Library
Access to unprotected 2‐cyano‐glycals via a mild palladium‐catalyzed cyanation of
protecting groups‐free 2‐iodoglycals in aqueous media has been developed. Diverse glycal …

Synthesis of d-glyco-alkynone derivatives via carbonylative Sonogashira reaction

MP Darbem, CHA Esteves, IM de Oliveira, JS Reis… - RSC …, 2019 - pubs.rsc.org
A carbonylative Sonogashira coupling approach to the synthesis of glyco-alkynones is
described. Eighteen examples were obtained in moderate do nearly quantitative yields …

Synthesis of glycosyl azides and their applications using CuAAC click chemistry to generate bis-and tris (triazolyl) glycosyl derivatives

A Shamim, SNS Vasconcelos, IM de Oliveira… - …, 2017 - thieme-connect.com
2, 3-Unsaturated C-(triazolyl) glycosyl acetates have been synthesized from 3, 4, 6-tri-O-
acetyl-d-glucal using C-glycosylation and click chemistry and were then used in a palladium …

Glycosamine Derivatives through Metal‐Catalyzed C− N Bond Formation on Protected and Unprotected 2‐Iodoglycals

M Malinowski, C Banoun… - European Journal of …, 2021 - Wiley Online Library
Glycosamines are important building blocks of natural biopolymers. The development of
synthetic routes to such glycoside family is of big interest in terms of biological application …

Recent advances in the radiation chemistry of destructured starch and other glucans as model compounds

D Khandal, S Fatahiyah Mohamad, X Coqueret - 2021 - books.rsc.org
This chapter overviews the influence of radiation processing applied to thermoplastic starch
and some other glucans in blends prepared with various types of plasticizers and additives …