Alkene functionalisation is a powerful strategy that has enabled access to a wide array of
compounds including valuable pharmaceuticals and agrochemicals. The reactivity of the …

This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

Herein, we describe nickel-catalyzed nitrile hydroboration with pinacolborane, wherein a
tethered NHC–pyridonate ligand enables efficient catalysis (5 mol%[Ni],≤ 6 h reaction time) …

In nickel-catalyzed cross-coupling reactions involving alkyl substrates, catalysts supported
by N-donor ligands are proposed to involve paramagnetic Ni (I) and Ni (III) species as key …

AT‐shaped Pt0 complex with a diphosphine‐borane (DPB) ligand was prepared. The Pt→ B
interaction enhances the electrophilicity of the metal and triggers the addition of Lewis bases …

Abstract Anionic [Pd (0)− X]− ate complex were proposed as key intermediates in Pd‐
catalyzed cross‐coupling for decades, but their isolation remained elusive. Herein, a …

Aminoalcohols are an easily available, highly diverse, and inexpensive class of ligands with
numerous applications in biological and technological contexts of metal–ligand mediated …

A comparison of catalytic activity of a series of ruthenium (II)-NNC pincer type complexes
bearing unsymmetrical pincer ligands NNRCR′(R= Me, OMe and R′= H, Me) with protic …

The catalytic cycloisomerization of nucleophile-functionalized alkynes is a useful method for
the synthesis of heterocyclic compounds with 100% atom economy. Group 8 catalysts give …

Anionic Pt (0) and Pd (0) complexes with unprecedented trigonal-bipyramidal geometry
have been prepared and thoroughly characterized by experimental and computational …