Propargylamines are a versatile class of compounds which find broad application in many
fields of chemistry. This review aims to describe the different strategies developed so far for …

Chiral molecules containing asymmetric carbon centers bonded with nitrogen are ubiquitous
in nature and also form important structural fragments in both natural and man-made …

The success of phosphine-oxazoline ligands (PHOX) inspired the progress in P-oxazoline
ligand families by modifying either the ligand backbone, the electronic and/or steric …

In the last few decades, the use of transition metals in organic synthesis has become
commonplace. 1 A distinct group of late transition metals, the so-called coinage metals, are …

Controlling regio-and enantioselectivity in C–H functionalization reactions is of paramount
importance due to their versatile synthetic utilities. Herein, we describe a new approach for …

Methods for enantioselective C–C bond constructions via additions to imines and related
compounds are reviewed, with an emphasis on the most recent efforts involving asymmetric …

β2-Amino carbonyls, an α-substituted β-amino scaffold, hold a prominent place in the
development of new pharmaceuticals and peptidomimetics. Herein, we report a highly …

We describe the first efficient, direct asymmetric Mannich reactions with malonates and N-
Boc aryl and alkyl imines by cooperative hydrogen-bonding catalysis with a cinchona …

Enantioselective Silver-Catalyzed Transformations | Chemical Reviews ACS ACS Publications
C&EN CAS Find my institution Log In Chemical Reviews ACS Publications. Most Trusted. Most …

This review highlights a number of recent developments in the field of main group
enantioselective catalysis. Many essential transformations can be effected catalytically such …