Metal–organic cages are versatile supramolecular architectures, fulfilling various distinct
roles in the mediation of catalysed chemical reactions. M n L2 n cages have become …

A heteroleptic [Pd2L2L'2] 4+ coordination cage containing a photoswitchable azobenzene-
derived ligand catalyzes the Michael addition reaction between methyl vinyl ketone and …

Desymmetrization of a symmetric skeleton enables late-stage functionalization of molecules.
However, reagent-controlled desymmetrization by site-selective reactions of symmetric …

The unique high surface area and tunable cavity size endow metal–organic cages (MOCs)
with superior performance and broad application in gas adsorption and separation. Over the …

Metal‐organic cages (MOCs) are popular host architectures assembled from ligands and
metal ions/nodes. Assembling structurally complex, low‐symmetry MOCs with anisotropic …

Spin-crossover (SCO) coordination cages are at the forefront of research for their potential in
crafting next-generation molecular devices. However, due to the scarcity of SCO hosts and …

Imine self-assembly stands as a potent strategy for the preparation of molecular organic
cages. However, challenges persist, such as water insolubility and limited recognition …

While chiral molecular rotors have unique frames and cavities to possibly generate
switchable chiroptical functions, it still remains a formidable challenge to precisely restrict …

We designed and synthesized an amide-based monomer decorated with furan as the diene
unit and maleimide as the dienophile unit at its termini. Single-crystal X-ray diffraction …

Chiral coordination molecular cages/capsules with discrete nanoconfined chiral cavities
demonstrate significant potential applications across various fields. In this study, we utilized …