Ligand design is becoming an increasingly important part of the synthetic activity in
chemistry. This is of course because of the subtle control that ligands exert on the metal …

The combination of reaction-oriented electrochemistry with species-focussed spectroscopy
in spectroelectrochemistry (SEC) allows for a more complete analysis of single and multiple …

Ligands in coordination chemistry and homogeneous catalysis are traditionally “static”
spectators that do not actively participate in the catalytic cycle. However, such classic …

Cooperative catalysis with first‐row transition metals holds much promise for future
developments regarding sustainable, selective transformations, including eg alkenes …

The application of a dendrimer in a redox‐switchable catalytic process is reported. A
monomeric and the corresponding dendritic ferrocenylphosphane ligand were used to …

Das Ligandendesign gewinnt auf dem Gebiet der chemischen Synthese immer mehr an
Bedeutung, denn mit Hilfe von speziellen Liganden lassen sich die Eigenschaften von …

High yielding syntheses of 1‐(ferrocenylmethyl)‐3‐mesitylimidazolium iodide (1) and 1‐
(ferrocenylmethyl)‐3‐mesitylimidazol‐2‐ylidene (2) were developed. Complexation of 2 to …

Two naphthalene‐diimide (NDI) bis‐imidazolium salts have been used as N‐heterocyclic
carbene (NHC) precursors for the preparation of NDI‐functionalized complexes of rhodium …

The present report develops the idea that an N‐heterocyclic carbene incorporating a remote
anionic functionality—here, a malonate group—as a backbone component of its heterocyclic …

The synthesis, structure, and full characterization of a redox‐switchable germylene based on
a [3] ferrocenophane ligand arrangement,[Fc (NMes) 2Ge](4), is presented. The mesityl …